Highly selective luminescent sensing of xylene isomers by a water stable Zn-organic framework

Jingya Zhang; Xiaoping Zhang; Jinghuo Chen; Chenghua Deng; Na Xu; Wei Shi; Peng Cheng

doi:10.1016/j.inoche.2016.04.013

Highly selective luminescent sensing of xylene isomers by a water stable Zn-organic framework

Jingya Zhang, Xiaoping Zhang, Jinghuo Chen, Chenghua Deng, Na Xu, Wei Shi, Peng Cheng

Nankai University

Research output: Contribution to journal › Article › peer-review

Abstract

A new Zn(II) metal-organic framework was synthesized with 5-nitro-1,2,3-benzenetricarboxylic acid and auxiliary triazole ligand via hydrothermal method, namely, {[Zn_2.5(nbta)(trz)₂(H₂O)]·3H₂O}_n (1), where H₃nbta = 5-nitro-1,2,3-benzenetricarboxylic acid and Htrz = 1H-1,2,4-triazole. 1 shows high thermal stability up to 150 °C under air atmosphere and water stability with the pH range from 1 to 12. Luminescent study shows that 1 displays a high-sensitivity sensing function for p-xylene in the three kinds of xylene isomers.

Original language	English
Pages (from-to)	1-3
Number of pages	3
Journal	Inorganic Chemistry Communications
Volume	69
DOIs	https://doi.org/10.1016/j.inoche.2016.04.013
Publication status	Published - 1 Jul 2016
Externally published	Yes

Keywords

Luminescent
m-xylene
o-xylene
p-xylene
Xylene isomers
Zn-MOF

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10.1016/j.inoche.2016.04.013

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title = "Highly selective luminescent sensing of xylene isomers by a water stable Zn-organic framework",

abstract = "A new Zn(II) metal-organic framework was synthesized with 5-nitro-1,2,3-benzenetricarboxylic acid and auxiliary triazole ligand via hydrothermal method, namely, {[Zn2.5(nbta)(trz)2(H2O)]·3H2O}n (1), where H3nbta = 5-nitro-1,2,3-benzenetricarboxylic acid and Htrz = 1H-1,2,4-triazole. 1 shows high thermal stability up to 150 °C under air atmosphere and water stability with the pH range from 1 to 12. Luminescent study shows that 1 displays a high-sensitivity sensing function for p-xylene in the three kinds of xylene isomers.",

keywords = "Luminescent, m-xylene, o-xylene, p-xylene, Xylene isomers, Zn-MOF",

author = "Jingya Zhang and Xiaoping Zhang and Jinghuo Chen and Chenghua Deng and Na Xu and Wei Shi and Peng Cheng",

year = "2016",

month = jul,

day = "1",

doi = "10.1016/j.inoche.2016.04.013",

language = "English",

volume = "69",

pages = "1--3",

journal = "Inorganic Chemistry Communications",

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TY - JOUR

T1 - Highly selective luminescent sensing of xylene isomers by a water stable Zn-organic framework

AU - Zhang, Jingya

AU - Zhang, Xiaoping

AU - Chen, Jinghuo

AU - Deng, Chenghua

AU - Xu, Na

AU - Shi, Wei

AU - Cheng, Peng

PY - 2016/7/1

Y1 - 2016/7/1

N2 - A new Zn(II) metal-organic framework was synthesized with 5-nitro-1,2,3-benzenetricarboxylic acid and auxiliary triazole ligand via hydrothermal method, namely, {[Zn2.5(nbta)(trz)2(H2O)]·3H2O}n (1), where H3nbta = 5-nitro-1,2,3-benzenetricarboxylic acid and Htrz = 1H-1,2,4-triazole. 1 shows high thermal stability up to 150 °C under air atmosphere and water stability with the pH range from 1 to 12. Luminescent study shows that 1 displays a high-sensitivity sensing function for p-xylene in the three kinds of xylene isomers.

AB - A new Zn(II) metal-organic framework was synthesized with 5-nitro-1,2,3-benzenetricarboxylic acid and auxiliary triazole ligand via hydrothermal method, namely, {[Zn2.5(nbta)(trz)2(H2O)]·3H2O}n (1), where H3nbta = 5-nitro-1,2,3-benzenetricarboxylic acid and Htrz = 1H-1,2,4-triazole. 1 shows high thermal stability up to 150 °C under air atmosphere and water stability with the pH range from 1 to 12. Luminescent study shows that 1 displays a high-sensitivity sensing function for p-xylene in the three kinds of xylene isomers.

KW - Luminescent

KW - m-xylene

KW - o-xylene

KW - p-xylene

KW - Xylene isomers

KW - Zn-MOF

UR - http://www.scopus.com/inward/record.url?scp=84964582955&partnerID=8YFLogxK

U2 - 10.1016/j.inoche.2016.04.013

DO - 10.1016/j.inoche.2016.04.013

M3 - Article

AN - SCOPUS:84964582955

SN - 1387-7003

VL - 69

SP - 1

EP - 3

JO - Inorganic Chemistry Communications

JF - Inorganic Chemistry Communications

ER -

Highly selective luminescent sensing of xylene isomers by a water stable Zn-organic framework

Abstract

Keywords

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