TY - JOUR
T1 - Hydrophobic pillared square grids for selective removal of CO2 from simulated flue gas
AU - Elsaidi, Sameh K.
AU - Mohamed, Mona H.
AU - Schaef, Herbert T.
AU - Kumar, Amrit
AU - Lusi, Matteo
AU - Pham, Tony
AU - Forrest, Katherine A.
AU - Space, Brian
AU - Xu, Wenqian
AU - Halder, Gregory J.
AU - Liu, Jun
AU - Zaworotko, Michael J.
AU - Thallapally, Praveen K.
N1 - Publisher Copyright:
© The Royal Society of Chemistry 2015.
PY - 2015
Y1 - 2015
N2 - Capture of CO2 from flue gas is considered to be a feasible approach to mitigate the effects of anthropogenic emission of CO2. Herein we report that an isostructural family of metal organic materials (MOMs) of general formula [M(linker)2(pillar)], linker = pyrazine, pillar = hexaflourosilicate and M = Zn, Cu, Ni and Co exhibits highly selective removal of CO2 from dry and wet simulated flue gas. Two members of the family, M = Ni and Co, SIFSIX-3-Ni and SIFSIX-3-Co, respectively, are reported for the first time and compared with the previously reported Zn and Cu analogs.
AB - Capture of CO2 from flue gas is considered to be a feasible approach to mitigate the effects of anthropogenic emission of CO2. Herein we report that an isostructural family of metal organic materials (MOMs) of general formula [M(linker)2(pillar)], linker = pyrazine, pillar = hexaflourosilicate and M = Zn, Cu, Ni and Co exhibits highly selective removal of CO2 from dry and wet simulated flue gas. Two members of the family, M = Ni and Co, SIFSIX-3-Ni and SIFSIX-3-Co, respectively, are reported for the first time and compared with the previously reported Zn and Cu analogs.
UR - http://www.scopus.com/inward/record.url?scp=84944342680&partnerID=8YFLogxK
U2 - 10.1039/c5cc06577a
DO - 10.1039/c5cc06577a
M3 - Article
AN - SCOPUS:84944342680
SN - 1359-7345
VL - 51
SP - 15530
EP - 15533
JO - Chemical Communications
JF - Chemical Communications
IS - 85
ER -
