Hydrophobic pillared square grids for selective removal of CO2 from simulated flue gas

Sameh K. Elsaidi; Mona H. Mohamed; Herbert T. Schaef; Amrit Kumar; Matteo Lusi; Tony Pham; Katherine A. Forrest; Brian Space; Wenqian Xu; Gregory J. Halder; Jun Liu; Michael J. Zaworotko; Praveen K. Thallapally

doi:10.1039/c5cc06577a

Hydrophobic pillared square grids for selective removal of CO₂ from simulated flue gas

Sameh K. Elsaidi
, Mona H. Mohamed
, Herbert T. Schaef
, Amrit Kumar
, Matteo Lusi
, Tony Pham
, Katherine A. Forrest
, Brian Space
, Wenqian Xu
, Gregory J. Halder
, Jun Liu
, Michael J. Zaworotko
, Praveen K. Thallapally

Department of Chemical Sciences

Research output: Contribution to journal › Article › peer-review

Abstract

Capture of CO₂ from flue gas is considered to be a feasible approach to mitigate the effects of anthropogenic emission of CO₂. Herein we report that an isostructural family of metal organic materials (MOMs) of general formula [M(linker)2(pillar)], linker = pyrazine, pillar = hexaflourosilicate and M = Zn, Cu, Ni and Co exhibits highly selective removal of CO₂ from dry and wet simulated flue gas. Two members of the family, M = Ni and Co, SIFSIX-3-Ni and SIFSIX-3-Co, respectively, are reported for the first time and compared with the previously reported Zn and Cu analogs.

Original language	English
Pages (from-to)	15530-15533
Number of pages	4
Journal	Chemical Communications
Volume	51
Issue number	85
DOIs	https://doi.org/10.1039/c5cc06577a
Publication status	Published - 2015

UN SDGs

This output contributes to the following UN Sustainable Development Goals (SDGs)

SDG 13 Climate Action

Access to Document

10.1039/c5cc06577a

Cite this

@article{846a74b7eca64f3a94b643dcbd9ed18b,

title = "Hydrophobic pillared square grids for selective removal of CO2 from simulated flue gas",

abstract = "Capture of CO2 from flue gas is considered to be a feasible approach to mitigate the effects of anthropogenic emission of CO2. Herein we report that an isostructural family of metal organic materials (MOMs) of general formula [M(linker)2(pillar)], linker = pyrazine, pillar = hexaflourosilicate and M = Zn, Cu, Ni and Co exhibits highly selective removal of CO2 from dry and wet simulated flue gas. Two members of the family, M = Ni and Co, SIFSIX-3-Ni and SIFSIX-3-Co, respectively, are reported for the first time and compared with the previously reported Zn and Cu analogs.",

author = "Elsaidi, \{Sameh K.\} and Mohamed, \{Mona H.\} and Schaef, \{Herbert T.\} and Amrit Kumar and Matteo Lusi and Tony Pham and Forrest, \{Katherine A.\} and Brian Space and Wenqian Xu and Halder, \{Gregory J.\} and Jun Liu and Zaworotko, \{Michael J.\} and Thallapally, \{Praveen K.\}",

note = "Publisher Copyright: {\textcopyright} The Royal Society of Chemistry 2015.",

year = "2015",

doi = "10.1039/c5cc06577a",

language = "English",

volume = "51",

pages = "15530--15533",

journal = "Chemical Communications",

issn = "1359-7345",

number = "85",

}

TY - JOUR

T1 - Hydrophobic pillared square grids for selective removal of CO2 from simulated flue gas

AU - Elsaidi, Sameh K.

AU - Mohamed, Mona H.

AU - Schaef, Herbert T.

AU - Kumar, Amrit

AU - Lusi, Matteo

AU - Pham, Tony

AU - Forrest, Katherine A.

AU - Space, Brian

AU - Xu, Wenqian

AU - Halder, Gregory J.

AU - Liu, Jun

AU - Zaworotko, Michael J.

AU - Thallapally, Praveen K.

PY - 2015

Y1 - 2015

N2 - Capture of CO2 from flue gas is considered to be a feasible approach to mitigate the effects of anthropogenic emission of CO2. Herein we report that an isostructural family of metal organic materials (MOMs) of general formula [M(linker)2(pillar)], linker = pyrazine, pillar = hexaflourosilicate and M = Zn, Cu, Ni and Co exhibits highly selective removal of CO2 from dry and wet simulated flue gas. Two members of the family, M = Ni and Co, SIFSIX-3-Ni and SIFSIX-3-Co, respectively, are reported for the first time and compared with the previously reported Zn and Cu analogs.

AB - Capture of CO2 from flue gas is considered to be a feasible approach to mitigate the effects of anthropogenic emission of CO2. Herein we report that an isostructural family of metal organic materials (MOMs) of general formula [M(linker)2(pillar)], linker = pyrazine, pillar = hexaflourosilicate and M = Zn, Cu, Ni and Co exhibits highly selective removal of CO2 from dry and wet simulated flue gas. Two members of the family, M = Ni and Co, SIFSIX-3-Ni and SIFSIX-3-Co, respectively, are reported for the first time and compared with the previously reported Zn and Cu analogs.

UR - https://www.scopus.com/pages/publications/84944342680

U2 - 10.1039/c5cc06577a

DO - 10.1039/c5cc06577a

M3 - Article

AN - SCOPUS:84944342680

SN - 1359-7345

VL - 51

SP - 15530

EP - 15533

JO - Chemical Communications

JF - Chemical Communications

IS - 85

ER -

Hydrophobic pillared square grids for selective removal of CO₂ from simulated flue gas

Abstract

UN SDGs

Access to Document

Other files and links

Fingerprint

Cite this