Improved hydrogen production from formic acid on a Pd/C catalyst doped by potassium

Dmitri A. Bulushev; Lijun Jia; Sergey Beloshapkin; Julian R.H. Ross

doi:10.1039/c2cc31027a

Improved hydrogen production from formic acid on a Pd/C catalyst doped by potassium

Dmitri A. Bulushev, Lijun Jia, Sergey Beloshapkin, Julian R.H. Ross

Retired Staff

University of Limerick

Research output: Contribution to journal › Article › peer-review

Abstract

The rate of hydrogen production from vapour-phase formic acid decomposition can be increased by 1–2 orders of magnitude by doping a Pd/C catalyst with potassium ions. Surface potassium formate and/or bicarbonate species could be involved in the rate-determining step of this reaction.

Original language	English
Pages (from-to)	4184-4186
Number of pages	3
Journal	Chemical Communications
Volume	48
Issue number	35
DOIs	https://doi.org/10.1039/c2cc31027a
Publication status	Published - 2 Apr 2012

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title = "Improved hydrogen production from formic acid on a Pd/C catalyst doped by potassium",

abstract = "The rate of hydrogen production from vapour-phase formic acid decomposition can be increased by 1–2 orders of magnitude by doping a Pd/C catalyst with potassium ions. Surface potassium formate and/or bicarbonate species could be involved in the rate-determining step of this reaction.",

author = "Bulushev, {Dmitri A.} and Lijun Jia and Sergey Beloshapkin and Ross, {Julian R.H.}",

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AU - Bulushev, Dmitri A.

AU - Jia, Lijun

AU - Beloshapkin, Sergey

AU - Ross, Julian R.H.

PY - 2012/4/2

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N2 - The rate of hydrogen production from vapour-phase formic acid decomposition can be increased by 1–2 orders of magnitude by doping a Pd/C catalyst with potassium ions. Surface potassium formate and/or bicarbonate species could be involved in the rate-determining step of this reaction.

AB - The rate of hydrogen production from vapour-phase formic acid decomposition can be increased by 1–2 orders of magnitude by doping a Pd/C catalyst with potassium ions. Surface potassium formate and/or bicarbonate species could be involved in the rate-determining step of this reaction.

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U2 - 10.1039/c2cc31027a

DO - 10.1039/c2cc31027a

M3 - Article

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AN - SCOPUS:84859322266

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VL - 48

SP - 4184

EP - 4186

JO - Chemical Communications

JF - Chemical Communications

IS - 35

ER -

Improved hydrogen production from formic acid on a Pd/C catalyst doped by potassium

Abstract

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