TY - JOUR
T1 - Independent but additive effects of fluorine and nitrogen substitution on properties of a calcium aluminosilicate glass
AU - Hanifi, Amir Reza
AU - Genson, Annäik
AU - Pomeroy, Michael J.
AU - Hampshire, Stuart
PY - 2012/2
Y1 - 2012/2
N2 - The effects of fluorine and nitrogen substitution for oxygen in a calcium aluminosilicate glass have been examined. Twelve glasses in the Ca-Si-Al-O-N-F system, with constant cation ratio, have been prepared and characterized with respect to density, molar volume (MV), fractional glass compactness (C), Young's modulus (E), microhardness (μHv), and glass transition temperature (T g). Linear regression analysis of the property data with respect to nitrogen and fluorine substitution for oxygen strongly indicates that each affects property values independent of each other. Nitrogen substitution decreases MV and increases C, E, μHv, and Tgvalues due to the greater network connectivity associated with tri-coordinated nitrogen. Fluorine substitution, which reduces network connectivity, decreases Tgvalues as might be expected. However, MV, C, E, and μHv are little affected by increases in fluorine content. The vastly different effects of nitrogen and fluorine on E and μHv are due to the manner in which their substitution for oxygen affects glass free volume and thus fractional glass compactness (i.e. atomic packing density). Differences in the effects of N and F substitution on Tgreflect their different effects on glass crosslink density. A method for calculating crosslink density is presented here, and the need for this method to take into account the ratio of network forming to network modifying aluminum is discussed.
AB - The effects of fluorine and nitrogen substitution for oxygen in a calcium aluminosilicate glass have been examined. Twelve glasses in the Ca-Si-Al-O-N-F system, with constant cation ratio, have been prepared and characterized with respect to density, molar volume (MV), fractional glass compactness (C), Young's modulus (E), microhardness (μHv), and glass transition temperature (T g). Linear regression analysis of the property data with respect to nitrogen and fluorine substitution for oxygen strongly indicates that each affects property values independent of each other. Nitrogen substitution decreases MV and increases C, E, μHv, and Tgvalues due to the greater network connectivity associated with tri-coordinated nitrogen. Fluorine substitution, which reduces network connectivity, decreases Tgvalues as might be expected. However, MV, C, E, and μHv are little affected by increases in fluorine content. The vastly different effects of nitrogen and fluorine on E and μHv are due to the manner in which their substitution for oxygen affects glass free volume and thus fractional glass compactness (i.e. atomic packing density). Differences in the effects of N and F substitution on Tgreflect their different effects on glass crosslink density. A method for calculating crosslink density is presented here, and the need for this method to take into account the ratio of network forming to network modifying aluminum is discussed.
UR - http://www.scopus.com/inward/record.url?scp=84856558152&partnerID=8YFLogxK
U2 - 10.1111/j.1551-2916.2011.05001.x
DO - 10.1111/j.1551-2916.2011.05001.x
M3 - Article
AN - SCOPUS:84856558152
SN - 0002-7820
VL - 95
SP - 600
EP - 606
JO - Journal of the American Ceramic Society
JF - Journal of the American Ceramic Society
IS - 2
ER -