Influence of Zirconia Addition on the Crystallization Kinetics of a Y-Si-Al-O-N Glass

P. Vomacka; R. Ramesh; S. Hampshire

doi:10.1016/0955-2219(96)00049-0

Influence of Zirconia Addition on the Crystallization Kinetics of a Y-Si-Al-O-N Glass

P. Vomacka
, R. Ramesh
, S. Hampshire

Retired Staff

Research output: Contribution to journal › Article › peer-review

Abstract

The crystallization behaviour of YSiAlON glasses with and without ZrO₂ additives, prepared by melting at 1700°C, were studied by means of differential scanning calorimetry, scanning microscopy and X-ray powder diffraction analysis. The optimum nucleation temperatures were determined to be Tg + 65°C and Tg + 50°C for the ZrO₂-free and the ZrO₂-containing glass, respectively. The crystallization of the glasses was found to be dominated by the surface mechanism of nucleation and growth. The added zirconia acted as a growth modifier rather than a nucleating agent.

Original language	English
Pages (from-to)	1253-1262
Number of pages	10
Journal	Journal of the European Ceramic Society
Volume	16
Issue number	11
DOIs	https://doi.org/10.1016/0955-2219(96)00049-0
Publication status	Published - 1996

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title = "Influence of Zirconia Addition on the Crystallization Kinetics of a Y-Si-Al-O-N Glass",

abstract = "The crystallization behaviour of YSiAlON glasses with and without ZrO2 additives, prepared by melting at 1700°C, were studied by means of differential scanning calorimetry, scanning microscopy and X-ray powder diffraction analysis. The optimum nucleation temperatures were determined to be Tg + 65°C and Tg + 50°C for the ZrO2-free and the ZrO2-containing glass, respectively. The crystallization of the glasses was found to be dominated by the surface mechanism of nucleation and growth. The added zirconia acted as a growth modifier rather than a nucleating agent.",

author = "P. Vomacka and R. Ramesh and S. Hampshire",

year = "1996",

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AU - Vomacka, P.

AU - Ramesh, R.

AU - Hampshire, S.

PY - 1996

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N2 - The crystallization behaviour of YSiAlON glasses with and without ZrO2 additives, prepared by melting at 1700°C, were studied by means of differential scanning calorimetry, scanning microscopy and X-ray powder diffraction analysis. The optimum nucleation temperatures were determined to be Tg + 65°C and Tg + 50°C for the ZrO2-free and the ZrO2-containing glass, respectively. The crystallization of the glasses was found to be dominated by the surface mechanism of nucleation and growth. The added zirconia acted as a growth modifier rather than a nucleating agent.

AB - The crystallization behaviour of YSiAlON glasses with and without ZrO2 additives, prepared by melting at 1700°C, were studied by means of differential scanning calorimetry, scanning microscopy and X-ray powder diffraction analysis. The optimum nucleation temperatures were determined to be Tg + 65°C and Tg + 50°C for the ZrO2-free and the ZrO2-containing glass, respectively. The crystallization of the glasses was found to be dominated by the surface mechanism of nucleation and growth. The added zirconia acted as a growth modifier rather than a nucleating agent.

UR - https://www.scopus.com/pages/publications/0001554988

U2 - 10.1016/0955-2219(96)00049-0

DO - 10.1016/0955-2219(96)00049-0

M3 - Article

AN - SCOPUS:0001554988

SN - 0955-2219

VL - 16

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JO - Journal of the European Ceramic Society

JF - Journal of the European Ceramic Society

IS - 11

ER -

Influence of Zirconia Addition on the Crystallization Kinetics of a Y-Si-Al-O-N Glass

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