Interpenetration of covalent and noncovalent networks in the crystal structures of ([M(4, 4′ -bipyridine)2(NO3)2]·2p -nitroanilinen where M=Co, 1, Ni, 2, Zn, 3

B. Moulton; E. B. Rather; M. J. Zaworotko

doi:10.1016/S1463-0184(01)00023-5

Interpenetration of covalent and noncovalent networks in the crystal structures of ([M(4, 4′ -bipyridine)₂(NO₃)₂]·2p -nitroaniline_n where M=Co, 1, Ni, 2, Zn, 3

B. Moulton, E. B. Rather, M. J. Zaworotko

University of South Florida

Research output: Contribution to journal › Article › peer-review

Abstract

The synthesis and crystal structures of ([M(4,4′ -bipyridine)₂(NO₃)₂]·2p -nitroaniline)_n, M=Co, 1, Ni, 2, Zn, 3, are described. 1, 2 and 3 crystallize in the form of compounds that can be described as interpenetrating covalent and noncovalent networks. Analysis of the crystal packing in these compounds reveals that the p-nitroaniline molecules form a noncovalent network that is complementary from a topological perspective with [M(4,4′ -bipyridine)₂(NO₃)₂] networks, which exist as square grids. These structures are interpreted in the broader perspective of crystal engineering strategies and development of new hybrid materials.

Original language	English
Pages (from-to)	309-317
Number of pages	9
Journal	Crystal Engineering
Volume	4
Issue number	4
DOIs	https://doi.org/10.1016/S1463-0184(01)00023-5
Publication status	Published - Dec 2001
Externally published	Yes

Keywords

Coordination polymers
Crystal structure
Interpenetration
Nitroaniline
Noncovalent

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10.1016/S1463-0184(01)00023-5

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title = "Interpenetration of covalent and noncovalent networks in the crystal structures of ([M(4, 4′ -bipyridine)2(NO3)2]·2p -nitroanilinen where M=Co, 1, Ni, 2, Zn, 3",

abstract = "The synthesis and crystal structures of ([M(4,4′ -bipyridine)2(NO3)2]·2p -nitroaniline)n, M=Co, 1, Ni, 2, Zn, 3, are described. 1, 2 and 3 crystallize in the form of compounds that can be described as interpenetrating covalent and noncovalent networks. Analysis of the crystal packing in these compounds reveals that the p-nitroaniline molecules form a noncovalent network that is complementary from a topological perspective with [M(4,4′ -bipyridine)2(NO3)2] networks, which exist as square grids. These structures are interpreted in the broader perspective of crystal engineering strategies and development of new hybrid materials.",

keywords = "Coordination polymers, Crystal structure, Interpenetration, Nitroaniline, Noncovalent",

author = "B. Moulton and Rather, {E. B.} and Zaworotko, {M. J.}",

year = "2001",

month = dec,

doi = "10.1016/S1463-0184(01)00023-5",

language = "English",

volume = "4",

pages = "309--317",

journal = "Crystal Engineering",

issn = "1463-0184",

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TY - JOUR

T1 - Interpenetration of covalent and noncovalent networks in the crystal structures of ([M(4, 4′ -bipyridine)2(NO3)2]·2p -nitroanilinen where M=Co, 1, Ni, 2, Zn, 3

AU - Moulton, B.

AU - Rather, E. B.

AU - Zaworotko, M. J.

PY - 2001/12

Y1 - 2001/12

N2 - The synthesis and crystal structures of ([M(4,4′ -bipyridine)2(NO3)2]·2p -nitroaniline)n, M=Co, 1, Ni, 2, Zn, 3, are described. 1, 2 and 3 crystallize in the form of compounds that can be described as interpenetrating covalent and noncovalent networks. Analysis of the crystal packing in these compounds reveals that the p-nitroaniline molecules form a noncovalent network that is complementary from a topological perspective with [M(4,4′ -bipyridine)2(NO3)2] networks, which exist as square grids. These structures are interpreted in the broader perspective of crystal engineering strategies and development of new hybrid materials.

AB - The synthesis and crystal structures of ([M(4,4′ -bipyridine)2(NO3)2]·2p -nitroaniline)n, M=Co, 1, Ni, 2, Zn, 3, are described. 1, 2 and 3 crystallize in the form of compounds that can be described as interpenetrating covalent and noncovalent networks. Analysis of the crystal packing in these compounds reveals that the p-nitroaniline molecules form a noncovalent network that is complementary from a topological perspective with [M(4,4′ -bipyridine)2(NO3)2] networks, which exist as square grids. These structures are interpreted in the broader perspective of crystal engineering strategies and development of new hybrid materials.

KW - Coordination polymers

KW - Crystal structure

KW - Interpenetration

KW - Nitroaniline

KW - Noncovalent

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U2 - 10.1016/S1463-0184(01)00023-5

DO - 10.1016/S1463-0184(01)00023-5

M3 - Article

AN - SCOPUS:0035546747

SN - 1463-0184

VL - 4

SP - 309

EP - 317

JO - Crystal Engineering

JF - Crystal Engineering

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ER -

Interpenetration of covalent and noncovalent networks in the crystal structures of ([M(4, 4′ -bipyridine)₂(NO₃)₂]·2p -nitroaniline_n where M=Co, 1, Ni, 2, Zn, 3

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Keywords

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