TY - JOUR
T1 - Ionic liquid mediated preparation and X-ray crystal structure of [1-methylimidazolium]2[cis-MoO2(salicylato-O1,O2)2]
AU - Boutilier, Kelly
AU - MacGillivray, Leonard R.
AU - Subramanian, S.
AU - Zaworotko, Michael J.
PY - 1993/10
Y1 - 1993/10
N2 - The complex salt, [1-MeimH]2[cis-MoO2(sal)2], 1, (1-Meim=1-methylimidazole, sal=o-C6H4(C-) (COC-)) has been prepared by reacting Mo(CO)6 with molten 1-methyl imidazolium salicylate [1-MeimH][salH], and the structure of 1 has been determined by single crystal X-ray crystallography: triclinic, P-1, a=9.220(2), b=9.469(3), c=15.368(4)Å, α=105.04(4), β=99.48(3), γ=109.48(3)°, Z=2, Dcalc=1.60 g/cm. 2809 reflections with I>2.5σ(I) gave a final values of R=0.031 and Rw=0.041.
AB - The complex salt, [1-MeimH]2[cis-MoO2(sal)2], 1, (1-Meim=1-methylimidazole, sal=o-C6H4(C-) (COC-)) has been prepared by reacting Mo(CO)6 with molten 1-methyl imidazolium salicylate [1-MeimH][salH], and the structure of 1 has been determined by single crystal X-ray crystallography: triclinic, P-1, a=9.220(2), b=9.469(3), c=15.368(4)Å, α=105.04(4), β=99.48(3), γ=109.48(3)°, Z=2, Dcalc=1.60 g/cm. 2809 reflections with I>2.5σ(I) gave a final values of R=0.031 and Rw=0.041.
UR - http://www.scopus.com/inward/record.url?scp=0000597272&partnerID=8YFLogxK
U2 - 10.1007/BF01247239
DO - 10.1007/BF01247239
M3 - Article
AN - SCOPUS:0000597272
SN - 0277-8068
VL - 23
SP - 773
EP - 778
JO - Journal of Crystal and Molecular Structure
JF - Journal of Crystal and Molecular Structure
IS - 10
ER -