Ionic liquid mediated preparation and X-ray crystal structure of [1-methylimidazolium]2[cis-MoO2(salicylato-O1,O2)2]

Kelly Boutilier; Leonard R. MacGillivray; S. Subramanian; Michael J. Zaworotko

doi:10.1007/BF01247239

Ionic liquid mediated preparation and X-ray crystal structure of [1-methylimidazolium]₂[cis-MoO₂(salicylato-O¹,O²)₂]

Kelly Boutilier
, Leonard R. MacGillivray
, S. Subramanian
, Michael J. Zaworotko

Saint Mary's University Halifax

Research output: Contribution to journal › Article › peer-review

Abstract

The complex salt, [1-MeimH]₂[cis-MoO₂(sal)₂], 1, (1-Meim=1-methylimidazole, sal=o-C₆H₄(C^-) (COC^-)) has been prepared by reacting Mo(CO)₆ with molten 1-methyl imidazolium salicylate [1-MeimH][salH], and the structure of 1 has been determined by single crystal X-ray crystallography: triclinic, P-1, a=9.220(2), b=9.469(3), c=15.368(4)Å, α=105.04(4), β=99.48(3), γ=109.48(3)°, Z=2, D_calc=1.60 g/cm. 2809 reflections with I>2.5σ(I) gave a final values of R=0.031 and R_w=0.041.

Original language	English
Pages (from-to)	773-778
Number of pages	6
Journal	Journal of Crystal and Molecular Structure
Volume	23
Issue number	10
DOIs	https://doi.org/10.1007/BF01247239
Publication status	Published - Oct 1993
Externally published	Yes

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@article{984e6aa2c71542a39b19f0a8f859fbbb,

title = "Ionic liquid mediated preparation and X-ray crystal structure of [1-methylimidazolium]2[cis-MoO2(salicylato-O1,O2)2]",

abstract = "The complex salt, [1-MeimH]2[cis-MoO2(sal)2], 1, (1-Meim=1-methylimidazole, sal=o-C6H4(C-) (COC-)) has been prepared by reacting Mo(CO)6 with molten 1-methyl imidazolium salicylate [1-MeimH][salH], and the structure of 1 has been determined by single crystal X-ray crystallography: triclinic, P-1, a=9.220(2), b=9.469(3), c=15.368(4){\AA}, α=105.04(4), β=99.48(3), γ=109.48(3)°, Z=2, Dcalc=1.60 g/cm. 2809 reflections with I>2.5σ(I) gave a final values of R=0.031 and Rw=0.041.",

author = "Kelly Boutilier and MacGillivray, \{Leonard R.\} and S. Subramanian and Zaworotko, \{Michael J.\}",

year = "1993",

month = oct,

doi = "10.1007/BF01247239",

language = "English",

volume = "23",

pages = "773--778",

journal = "Journal of Crystal and Molecular Structure",

issn = "0277-8068",

number = "10",

}

TY - JOUR

T1 - Ionic liquid mediated preparation and X-ray crystal structure of [1-methylimidazolium]2[cis-MoO2(salicylato-O1,O2)2]

AU - Boutilier, Kelly

AU - MacGillivray, Leonard R.

AU - Subramanian, S.

AU - Zaworotko, Michael J.

PY - 1993/10

Y1 - 1993/10

N2 - The complex salt, [1-MeimH]2[cis-MoO2(sal)2], 1, (1-Meim=1-methylimidazole, sal=o-C6H4(C-) (COC-)) has been prepared by reacting Mo(CO)6 with molten 1-methyl imidazolium salicylate [1-MeimH][salH], and the structure of 1 has been determined by single crystal X-ray crystallography: triclinic, P-1, a=9.220(2), b=9.469(3), c=15.368(4)Å, α=105.04(4), β=99.48(3), γ=109.48(3)°, Z=2, Dcalc=1.60 g/cm. 2809 reflections with I>2.5σ(I) gave a final values of R=0.031 and Rw=0.041.

AB - The complex salt, [1-MeimH]2[cis-MoO2(sal)2], 1, (1-Meim=1-methylimidazole, sal=o-C6H4(C-) (COC-)) has been prepared by reacting Mo(CO)6 with molten 1-methyl imidazolium salicylate [1-MeimH][salH], and the structure of 1 has been determined by single crystal X-ray crystallography: triclinic, P-1, a=9.220(2), b=9.469(3), c=15.368(4)Å, α=105.04(4), β=99.48(3), γ=109.48(3)°, Z=2, Dcalc=1.60 g/cm. 2809 reflections with I>2.5σ(I) gave a final values of R=0.031 and Rw=0.041.

UR - https://www.scopus.com/pages/publications/0000597272

U2 - 10.1007/BF01247239

DO - 10.1007/BF01247239

M3 - Article

AN - SCOPUS:0000597272

SN - 0277-8068

VL - 23

SP - 773

EP - 778

JO - Journal of Crystal and Molecular Structure

JF - Journal of Crystal and Molecular Structure

IS - 10

ER -

Ionic liquid mediated preparation and X-ray crystal structure of [1-methylimidazolium]₂[cis-MoO₂(salicylato-O¹,O²)₂]

Abstract

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