Iron, copper and silver nanoparticles: Green synthesis using green and black tea leaves extracts and evaluation of antibacterial, antifungal and aflatoxin B1 adsorption activity

Muhammad Asif Asghar, Erum Zahir, Syed Muhammad Shahid, Muhammad Naseem Khan, Muhammad Arif Asghar, Javed Iqbal, Gavin Walker

Research output: Contribution to journalArticlepeer-review

Abstract

The present study was aimed to account an eco-friendly synthesis of iron (Fe), copper (Cu) and silver (Ag) nanoparticles (NPs) using green tea and black tea leaves extracts. Synthesized NPs were characterized using SEM, FTIR, EDX and UV/Vis spectroscopy techniques. Antibacterial activity of NPs was assessed against methicillin- and vancomycin-resistance Staphylococcus aureus strains. Antifungal activity was investigated against Aspergillus flavus and A. parasiticus fungal species. Adsorbent capability with aflatoxin B1 (AFB1) was also assessed in solution. Ag-NPs showed superior antibacterial/antifungal activities and reduced the aflatoxins production in comparison to Fe-NPs and Cu-NPs. Adsorption capability of all NPs with AFB1 contamination was found in the order of Fe-NPs > Cu-NPs > Ag-NPs. The equilibrium data showed the favorability of Langmuir isotherm with the adsorption capacity (131–139 ng/mg), Cu-NPs (114–118 ng/mg) and Ag-NPs (110–115 ng/mg). Thermodynamic parameters and kinetic studies revealed that adsorption process is spontaneous, endothermic and followed the pseudo-second order. These results suggest that the synthesized NPs could be effectively utilize as an alternative antibacterial/antifungal agent against diseases caused by multiple drug resistant pathogens. In addition, these metal NPs may be utilize as a possible aflatoxins adsorbent in human food and animal feed such as rice, wheat, maize, red chillies and poultry feed.

Original languageEnglish
Pages (from-to)98-107
Number of pages10
JournalLWT
Volume90
DOIs
Publication statusPublished - Apr 2018

Keywords

  • Adsorption
  • Antibacterial
  • Antifungal
  • Green synthesis
  • Metal nanoparticles

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