Local investigation of electronic structure modulation in BaPb xBi 1-xO 3 via highly spatially resolved low-loss electron energy loss spectroscopy

Ursel Bangert; A. Gutiérrez-Sosa; W. R. Flavell

Local investigation of electronic structure modulation in BaPb xBi 1-xO 3 via highly spatially resolved low-loss electron energy loss spectroscopy

Ursel Bangert
, A. Gutiérrez-Sosa
, W. R. Flavell

Retired Staff

University of Manchester

Research output: Contribution to journal › Article › peer-review

Abstract

BaPb _1-xBi _xO ₃ (BPBO) samples with x=1, 0. 25 and 0.5 have been studied using highly spatially resolved electron energy loss spectroscopy in the low loss energy range and energy dispersive X-ray (EDX) analysis. We have been able to identify crystallographic orientations and discover great inhomogeneities even within nanometre distances. We show the modulation of local electronic structure with local composition in BPBO phases with different nominal x. This enables us also to demonstrate the evolution of the metal-semiconductor transition as a function of x.

Original language	English (Ireland)
Pages (from-to)	537-540
Number of pages	4
Journal	Design and Nature
Volume	6
Publication status	Published - 2004
Event	Design and Nature II: Comparing Design in Nature with Science and Engineering - Rhodes, Greece Duration: 28 Jun 2004 → 30 Jun 2004

Cite this

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title = "Local investigation of electronic structure modulation in BaPb xBi 1-xO 3 via highly spatially resolved low-loss electron energy loss spectroscopy",

abstract = "BaPb 1-xBi xO 3 (BPBO) samples with x=1, 0. 25 and 0.5 have been studied using highly spatially resolved electron energy loss spectroscopy in the low loss energy range and energy dispersive X-ray (EDX) analysis. We have been able to identify crystallographic orientations and discover great inhomogeneities even within nanometre distances. We show the modulation of local electronic structure with local composition in BPBO phases with different nominal x. This enables us also to demonstrate the evolution of the metal-semiconductor transition as a function of x.",

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year = "2004",

language = "English (Ireland)",

volume = "6",

pages = "537--540",

journal = "Design and Nature",

issn = "1478-0585",

note = "Design and Nature II: Comparing Design in Nature with Science and Engineering ; Conference date: 28-06-2004 Through 30-06-2004",

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T1 - Local investigation of electronic structure modulation in BaPb xBi 1-xO 3 via highly spatially resolved low-loss electron energy loss spectroscopy

AU - Bangert, Ursel

AU - Gutiérrez-Sosa, A.

AU - Flavell, W. R.

PY - 2004

Y1 - 2004

N2 - BaPb 1-xBi xO 3 (BPBO) samples with x=1, 0. 25 and 0.5 have been studied using highly spatially resolved electron energy loss spectroscopy in the low loss energy range and energy dispersive X-ray (EDX) analysis. We have been able to identify crystallographic orientations and discover great inhomogeneities even within nanometre distances. We show the modulation of local electronic structure with local composition in BPBO phases with different nominal x. This enables us also to demonstrate the evolution of the metal-semiconductor transition as a function of x.

AB - BaPb 1-xBi xO 3 (BPBO) samples with x=1, 0. 25 and 0.5 have been studied using highly spatially resolved electron energy loss spectroscopy in the low loss energy range and energy dispersive X-ray (EDX) analysis. We have been able to identify crystallographic orientations and discover great inhomogeneities even within nanometre distances. We show the modulation of local electronic structure with local composition in BPBO phases with different nominal x. This enables us also to demonstrate the evolution of the metal-semiconductor transition as a function of x.

UR - https://www.scopus.com/pages/publications/7744231402

M3 - Article

AN - SCOPUS:7744231402

SN - 1478-0585

VL - 6

SP - 537

EP - 540

JO - Design and Nature

JF - Design and Nature

T2 - Design and Nature II: Comparing Design in Nature with Science and Engineering

Y2 - 28 June 2004 through 30 June 2004

ER -

Local investigation of electronic structure modulation in BaPb xBi 1-xO 3 via highly spatially resolved low-loss electron energy loss spectroscopy

Abstract

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