TY - JOUR
T1 - Monomeric, coloured germanium(II) and tin(II) di-t-butylamides, and the crystal and molecular structure of ge(NCMe2[CH2] 3CMe2)2
AU - Lappert, Michael F.
AU - Slade, Martin J.
AU - Atwood, Jerry L.
AU - Zaworotko, Michael J.
PY - 1980
Y1 - 1980
N2 - The orange (GeII) or maroon (SnII) bivalent group 4 metal di-t-butylamides were obtained from LiNBut2 and GeCl2·dioxan or SnCl2 in tetrahydrofuran, and are low melting diamagnetic, volatile, monomeric (cryoscopy in C6H 12), labile compounds (readily yielding ·NBut 2); X-ray analysis of the title compound to R = 0.091 shows that this related GeII amide is a monomer in the crystal with a long Ge-N bond of 1.885 Å and an NGeN angle of 111.4(5)°.
AB - The orange (GeII) or maroon (SnII) bivalent group 4 metal di-t-butylamides were obtained from LiNBut2 and GeCl2·dioxan or SnCl2 in tetrahydrofuran, and are low melting diamagnetic, volatile, monomeric (cryoscopy in C6H 12), labile compounds (readily yielding ·NBut 2); X-ray analysis of the title compound to R = 0.091 shows that this related GeII amide is a monomer in the crystal with a long Ge-N bond of 1.885 Å and an NGeN angle of 111.4(5)°.
UR - http://www.scopus.com/inward/record.url?scp=37049095617&partnerID=8YFLogxK
U2 - 10.1039/c39800000621
DO - 10.1039/c39800000621
M3 - Article
AN - SCOPUS:37049095617
SN - 0022-4936
SP - 621
EP - 622
JO - Journal of the Chemical Society, Chemical Communications
JF - Journal of the Chemical Society, Chemical Communications
IS - 13
ER -