N-[3-(4-Fluorobenzyl)-2,4-dioxo-1,3-diazaspiro[4.5]dec-8-yl] -2-methylbenzenesulfonamide

S. Jeyaseelan; M. Vinduvahini; M. Madaiah; Suman Bhattacharya; H. D. Revanasiddappa

doi:10.1107/S160053681105269X

N-[3-(4-Fluorobenzyl)-2,4-dioxo-1,3-diazaspiro[4.5]dec-8-yl] -2-methylbenzenesulfonamide

S. Jeyaseelan
, M. Vinduvahini
, M. Madaiah
, Suman Bhattacharya
, H. D. Revanasiddappa

Research output: Contribution to journal › Article › peer-review

Abstract

In the title compound, C ₂₂H ₂₄FN ₃O ₄S, the cyclohexane ring adopts a chair conformation and the five-membered ring is essentially planar, with a maximum deviation of 0.040(2) Å. The dihedral angles between the five-membered ring and the tolyl and fluorobenzene rings are 56.74(12) and 89.88(12)°, respectively. The two terminal benzene rings make a dihedral angle of 63.53(12)°. The crystal structure displays intermolecular C-H··· O and N-H··· O hydrogen bonds. An intramolecular C-H··· O hydrogen bond also occurs.

Original language	English
Pages (from-to)	o105-o106
Journal	Acta Crystallographica Section E: Structure Reports Online
Volume	68
Issue number	1
DOIs	https://doi.org/10.1107/S160053681105269X
Publication status	Published - Jan 2012
Externally published	Yes

Keywords

Data-to-parameter ratio = 13.2
Mean σ(C-C) = 0.003 Å
R factor = 0.043
Single-crystal X-ray study
T = 293 K
wR factor = 0.114

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@article{2057338f1f1c4137b244b831f2985e59,

title = "N-[3-(4-Fluorobenzyl)-2,4-dioxo-1,3-diazaspiro[4.5]dec-8-yl] -2-methylbenzenesulfonamide",

abstract = "In the title compound, C 22H 24FN 3O 4S, the cyclohexane ring adopts a chair conformation and the five-membered ring is essentially planar, with a maximum deviation of 0.040(2) {\AA}. The dihedral angles between the five-membered ring and the tolyl and fluorobenzene rings are 56.74(12) and 89.88(12)°, respectively. The two terminal benzene rings make a dihedral angle of 63.53(12)°. The crystal structure displays intermolecular C-H··· O and N-H··· O hydrogen bonds. An intramolecular C-H··· O hydrogen bond also occurs.",

keywords = "Data-to-parameter ratio = 13.2, Mean σ(C-C) = 0.003 {\AA}, R factor = 0.043, Single-crystal X-ray study, T = 293 K, wR factor = 0.114",

author = "S. Jeyaseelan and M. Vinduvahini and M. Madaiah and Suman Bhattacharya and Revanasiddappa, \{H. D.\}",

year = "2012",

month = jan,

doi = "10.1107/S160053681105269X",

language = "English",

volume = "68",

pages = "o105--o106",

journal = "Acta Crystallographica Section E: Structure Reports Online",

issn = "1600-5368",

number = "1",

}

TY - JOUR

T1 - N-[3-(4-Fluorobenzyl)-2,4-dioxo-1,3-diazaspiro[4.5]dec-8-yl] -2-methylbenzenesulfonamide

AU - Jeyaseelan, S.

AU - Vinduvahini, M.

AU - Madaiah, M.

AU - Bhattacharya, Suman

AU - Revanasiddappa, H. D.

PY - 2012/1

Y1 - 2012/1

N2 - In the title compound, C 22H 24FN 3O 4S, the cyclohexane ring adopts a chair conformation and the five-membered ring is essentially planar, with a maximum deviation of 0.040(2) Å. The dihedral angles between the five-membered ring and the tolyl and fluorobenzene rings are 56.74(12) and 89.88(12)°, respectively. The two terminal benzene rings make a dihedral angle of 63.53(12)°. The crystal structure displays intermolecular C-H··· O and N-H··· O hydrogen bonds. An intramolecular C-H··· O hydrogen bond also occurs.

AB - In the title compound, C 22H 24FN 3O 4S, the cyclohexane ring adopts a chair conformation and the five-membered ring is essentially planar, with a maximum deviation of 0.040(2) Å. The dihedral angles between the five-membered ring and the tolyl and fluorobenzene rings are 56.74(12) and 89.88(12)°, respectively. The two terminal benzene rings make a dihedral angle of 63.53(12)°. The crystal structure displays intermolecular C-H··· O and N-H··· O hydrogen bonds. An intramolecular C-H··· O hydrogen bond also occurs.

KW - Data-to-parameter ratio = 13.2

KW - Mean σ(C-C) = 0.003 Å

KW - R factor = 0.043

KW - Single-crystal X-ray study

KW - T = 293 K

KW - wR factor = 0.114

UR - https://www.scopus.com/pages/publications/84855377448

U2 - 10.1107/S160053681105269X

DO - 10.1107/S160053681105269X

M3 - Article

AN - SCOPUS:84855377448

SN - 1600-5368

VL - 68

SP - o105-o106

JO - Acta Crystallographica Section E: Structure Reports Online

JF - Acta Crystallographica Section E: Structure Reports Online

IS - 1

ER -

N-[3-(4-Fluorobenzyl)-2,4-dioxo-1,3-diazaspiro[4.5]dec-8-yl] -2-methylbenzenesulfonamide

Abstract

Keywords

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