Nanocrystalline doped ceria-zirconia fluorite-like solid solutions promoted by Pt: Structure, surface properties and catalytic performance in syngas generation

Vladislav A. Sadykov; Natalia Mezentseva; Galina Alikina; Anton Lukashevich; Vitalii Muzykantov; Tatiana Kuznetsova; Lubsan Batuev; Martin Fedotov; Ella Moroz; Dmitrii Zyuzin; Vera Kolko; Vladimir Kriventsov; Vyacheslav Ivanov; Andrei Boronin; Egor Pazhetnov; Vladimir Zaikovskii; Arcady Ishchenko; Vladimir Rogov; Julian Ross; Erhard Kemnitz

doi:10.1557/PROC-988-0988-QQ06-04

Nanocrystalline doped ceria-zirconia fluorite-like solid solutions promoted by Pt: Structure, surface properties and catalytic performance in syngas generation

Vladislav A. Sadykov, Natalia Mezentseva, Galina Alikina, Anton Lukashevich, Vitalii Muzykantov, Tatiana Kuznetsova, Lubsan Batuev, Martin Fedotov, Ella Moroz, Dmitrii Zyuzin, Vera Kolko, Vladimir Kriventsov, Vyacheslav Ivanov, Andrei Boronin, Egor Pazhetnov, Vladimir Zaikovskii, Arcady Ishchenko, Vladimir Rogov, Julian Ross, Erhard Kemnitz

Retired Staff

Research output: Chapter in Book/Report/Conference proceeding › Conference contribution › peer-review

Abstract

Nanocrystalline ceria-zirconia samples doped with rare-earth (Gd, Pr, Sm, La) cations were prepared via modified Pechini route. Effect of their real structure and surface composition characterized by a combination of sophisticated physical methods (XRD, TEM +EDX, EXAFS, WAXS, UV-Vis, XPS, SIMS) on the mobility and reactivity of the lattice oxygen estimated by oxygen isotope exchange, H₂, CH₄ and CO TPR was analyzed. For the reaction of acetone autothermal reforming into syngas, catalytic activity correlates rather well with the oxygen mobility controlled by the type and content of a dopant.

Original language	English
Title of host publication	Solid-State Chemistry of Inorganic Materials VI
Publisher	Materials Research Society
Pages	130-135
Number of pages	6
ISBN (Print)	9781604234336
DOIs	https://doi.org/10.1557/PROC-988-0988-QQ06-04
Publication status	Published - 2006
Event	2006 MRS Fall Meeting - Boston, MA, United States Duration: 27 Nov 2006 → 1 Dec 2006

Publication series

Name	Materials Research Society Symposium Proceedings
Volume	988
ISSN (Print)	0272-9172

Conference

Conference	2006 MRS Fall Meeting
Country/Territory	United States
City	Boston, MA
Period	27/11/06 → 1/12/06

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10.1557/PROC-988-0988-QQ06-04

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Sadykov, V. A., Mezentseva, N., Alikina, G., Lukashevich, A., Muzykantov, V., Kuznetsova, T., Batuev, L., Fedotov, M., Moroz, E., Zyuzin, D., Kolko, V., Kriventsov, V., Ivanov, V., Boronin, A., Pazhetnov, E., Zaikovskii, V., Ishchenko, A., Rogov, V., Ross, J., & Kemnitz, E. (2006). Nanocrystalline doped ceria-zirconia fluorite-like solid solutions promoted by Pt: Structure, surface properties and catalytic performance in syngas generation. In Solid-State Chemistry of Inorganic Materials VI (pp. 130-135). (Materials Research Society Symposium Proceedings; Vol. 988). Materials Research Society. https://doi.org/10.1557/PROC-988-0988-QQ06-04

Sadykov, Vladislav A. ; Mezentseva, Natalia ; Alikina, Galina et al. / Nanocrystalline doped ceria-zirconia fluorite-like solid solutions promoted by Pt : Structure, surface properties and catalytic performance in syngas generation. Solid-State Chemistry of Inorganic Materials VI. Materials Research Society, 2006. pp. 130-135 (Materials Research Society Symposium Proceedings).

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title = "Nanocrystalline doped ceria-zirconia fluorite-like solid solutions promoted by Pt: Structure, surface properties and catalytic performance in syngas generation",

abstract = "Nanocrystalline ceria-zirconia samples doped with rare-earth (Gd, Pr, Sm, La) cations were prepared via modified Pechini route. Effect of their real structure and surface composition characterized by a combination of sophisticated physical methods (XRD, TEM +EDX, EXAFS, WAXS, UV-Vis, XPS, SIMS) on the mobility and reactivity of the lattice oxygen estimated by oxygen isotope exchange, H2, CH4 and CO TPR was analyzed. For the reaction of acetone autothermal reforming into syngas, catalytic activity correlates rather well with the oxygen mobility controlled by the type and content of a dopant.",

author = "Sadykov, {Vladislav A.} and Natalia Mezentseva and Galina Alikina and Anton Lukashevich and Vitalii Muzykantov and Tatiana Kuznetsova and Lubsan Batuev and Martin Fedotov and Ella Moroz and Dmitrii Zyuzin and Vera Kolko and Vladimir Kriventsov and Vyacheslav Ivanov and Andrei Boronin and Egor Pazhetnov and Vladimir Zaikovskii and Arcady Ishchenko and Vladimir Rogov and Julian Ross and Erhard Kemnitz",

year = "2006",

doi = "10.1557/PROC-988-0988-QQ06-04",

language = "English",

isbn = "9781604234336",

series = "Materials Research Society Symposium Proceedings",

publisher = "Materials Research Society",

pages = "130--135",

booktitle = "Solid-State Chemistry of Inorganic Materials VI",

note = "2006 MRS Fall Meeting ; Conference date: 27-11-2006 Through 01-12-2006",

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Sadykov, VA, Mezentseva, N, Alikina, G, Lukashevich, A, Muzykantov, V, Kuznetsova, T, Batuev, L, Fedotov, M, Moroz, E, Zyuzin, D, Kolko, V, Kriventsov, V, Ivanov, V, Boronin, A, Pazhetnov, E, Zaikovskii, V, Ishchenko, A, Rogov, V, Ross, J & Kemnitz, E 2006, Nanocrystalline doped ceria-zirconia fluorite-like solid solutions promoted by Pt: Structure, surface properties and catalytic performance in syngas generation. in Solid-State Chemistry of Inorganic Materials VI. Materials Research Society Symposium Proceedings, vol. 988, Materials Research Society, pp. 130-135, 2006 MRS Fall Meeting, Boston, MA, United States, 27/11/06. https://doi.org/10.1557/PROC-988-0988-QQ06-04

Nanocrystalline doped ceria-zirconia fluorite-like solid solutions promoted by Pt: Structure, surface properties and catalytic performance in syngas generation. / Sadykov, Vladislav A.; Mezentseva, Natalia; Alikina, Galina et al.
Solid-State Chemistry of Inorganic Materials VI. Materials Research Society, 2006. p. 130-135 (Materials Research Society Symposium Proceedings; Vol. 988).

Research output: Chapter in Book/Report/Conference proceeding › Conference contribution › peer-review

TY - GEN

T1 - Nanocrystalline doped ceria-zirconia fluorite-like solid solutions promoted by Pt

T2 - 2006 MRS Fall Meeting

AU - Sadykov, Vladislav A.

AU - Mezentseva, Natalia

AU - Alikina, Galina

AU - Lukashevich, Anton

AU - Muzykantov, Vitalii

AU - Kuznetsova, Tatiana

AU - Batuev, Lubsan

AU - Fedotov, Martin

AU - Moroz, Ella

AU - Zyuzin, Dmitrii

AU - Kolko, Vera

AU - Kriventsov, Vladimir

AU - Ivanov, Vyacheslav

AU - Boronin, Andrei

AU - Pazhetnov, Egor

AU - Zaikovskii, Vladimir

AU - Ishchenko, Arcady

AU - Rogov, Vladimir

AU - Ross, Julian

AU - Kemnitz, Erhard

PY - 2006

Y1 - 2006

N2 - Nanocrystalline ceria-zirconia samples doped with rare-earth (Gd, Pr, Sm, La) cations were prepared via modified Pechini route. Effect of their real structure and surface composition characterized by a combination of sophisticated physical methods (XRD, TEM +EDX, EXAFS, WAXS, UV-Vis, XPS, SIMS) on the mobility and reactivity of the lattice oxygen estimated by oxygen isotope exchange, H2, CH4 and CO TPR was analyzed. For the reaction of acetone autothermal reforming into syngas, catalytic activity correlates rather well with the oxygen mobility controlled by the type and content of a dopant.

AB - Nanocrystalline ceria-zirconia samples doped with rare-earth (Gd, Pr, Sm, La) cations were prepared via modified Pechini route. Effect of their real structure and surface composition characterized by a combination of sophisticated physical methods (XRD, TEM +EDX, EXAFS, WAXS, UV-Vis, XPS, SIMS) on the mobility and reactivity of the lattice oxygen estimated by oxygen isotope exchange, H2, CH4 and CO TPR was analyzed. For the reaction of acetone autothermal reforming into syngas, catalytic activity correlates rather well with the oxygen mobility controlled by the type and content of a dopant.

UR - http://www.scopus.com/inward/record.url?scp=41549129007&partnerID=8YFLogxK

U2 - 10.1557/PROC-988-0988-QQ06-04

DO - 10.1557/PROC-988-0988-QQ06-04

M3 - Conference contribution

AN - SCOPUS:41549129007

SN - 9781604234336

T3 - Materials Research Society Symposium Proceedings

SP - 130

EP - 135

BT - Solid-State Chemistry of Inorganic Materials VI

PB - Materials Research Society

Y2 - 27 November 2006 through 1 December 2006

ER -

Sadykov VA, Mezentseva N, Alikina G, Lukashevich A, Muzykantov V, Kuznetsova T et al. Nanocrystalline doped ceria-zirconia fluorite-like solid solutions promoted by Pt: Structure, surface properties and catalytic performance in syngas generation. In Solid-State Chemistry of Inorganic Materials VI. Materials Research Society. 2006. p. 130-135. (Materials Research Society Symposium Proceedings). doi: 10.1557/PROC-988-0988-QQ06-04

Nanocrystalline doped ceria-zirconia fluorite-like solid solutions promoted by Pt: Structure, surface properties and catalytic performance in syngas generation

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