On the nature of factors determining reactivity of strongly bound surface species as intermediates in heterogeneous catalytic redox reactions

V. A. Sadykov; A. Ya Rozovskii; V. Y. Lunin; G. I. Lin; G. M. Alikina; G. A. Buchtiyarova; B. P. Zolotovskii; S. A. Beloshapkin

doi:10.1007/BF02475810

On the nature of factors determining reactivity of strongly bound surface species as intermediates in heterogeneous catalytic redox reactions

V. A. Sadykov, A. Ya Rozovskii, V. Y. Lunin, G. I. Lin, G. M. Alikina, G. A. Buchtiyarova, B. P. Zolotovskii, S. A. Beloshapkin

Research output: Contribution to journal › Article › peer-review

Abstract

The rate-limiting stage of heterogeneous catalytic redox reactions with participation of strongly bound surface species, such as nitrates, carbonates and sulfites, is the interaction of these heteroatomic oxidants with the reducing agents. It appears to be mainly determined by their bonding strength with the surface, being independent of the nature of the central atom (carbon, sulfur, nitrogen) and the energy of its bond with oxygen.

Original language	English
Pages (from-to)	337-341
Number of pages	5
Journal	Reaction Kinetics and Catalysis Letters
Volume	66
Issue number	2
DOIs	https://doi.org/10.1007/BF02475810
Publication status	Published - 1999
Externally published	Yes

Keywords

Klaus reaction
Mechanism of catalytic redox reactions
Methanol synthesis
Selective reduction of nitrogen oxides by hydrocarbons
Strongly bound intermediates

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10.1007/BF02475810

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Sadykov, V. A., Rozovskii, A. Y., Lunin, V. Y., Lin, G. I., Alikina, G. M., Buchtiyarova, G. A., Zolotovskii, B. P., & Beloshapkin, S. A. (1999). On the nature of factors determining reactivity of strongly bound surface species as intermediates in heterogeneous catalytic redox reactions. Reaction Kinetics and Catalysis Letters, 66(2), 337-341. https://doi.org/10.1007/BF02475810

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abstract = "The rate-limiting stage of heterogeneous catalytic redox reactions with participation of strongly bound surface species, such as nitrates, carbonates and sulfites, is the interaction of these heteroatomic oxidants with the reducing agents. It appears to be mainly determined by their bonding strength with the surface, being independent of the nature of the central atom (carbon, sulfur, nitrogen) and the energy of its bond with oxygen.",

keywords = "Klaus reaction, Mechanism of catalytic redox reactions, Methanol synthesis, Selective reduction of nitrogen oxides by hydrocarbons, Strongly bound intermediates",

author = "Sadykov, {V. A.} and Rozovskii, {A. Ya} and Lunin, {V. Y.} and Lin, {G. I.} and Alikina, {G. M.} and Buchtiyarova, {G. A.} and Zolotovskii, {B. P.} and Beloshapkin, {S. A.}",

year = "1999",

doi = "10.1007/BF02475810",

language = "English",

volume = "66",

pages = "337--341",

journal = "Reaction Kinetics and Catalysis Letters",

issn = "0133-1736",

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T1 - On the nature of factors determining reactivity of strongly bound surface species as intermediates in heterogeneous catalytic redox reactions

AU - Sadykov, V. A.

AU - Rozovskii, A. Ya

AU - Lunin, V. Y.

AU - Lin, G. I.

AU - Alikina, G. M.

AU - Buchtiyarova, G. A.

AU - Zolotovskii, B. P.

AU - Beloshapkin, S. A.

PY - 1999

Y1 - 1999

N2 - The rate-limiting stage of heterogeneous catalytic redox reactions with participation of strongly bound surface species, such as nitrates, carbonates and sulfites, is the interaction of these heteroatomic oxidants with the reducing agents. It appears to be mainly determined by their bonding strength with the surface, being independent of the nature of the central atom (carbon, sulfur, nitrogen) and the energy of its bond with oxygen.

AB - The rate-limiting stage of heterogeneous catalytic redox reactions with participation of strongly bound surface species, such as nitrates, carbonates and sulfites, is the interaction of these heteroatomic oxidants with the reducing agents. It appears to be mainly determined by their bonding strength with the surface, being independent of the nature of the central atom (carbon, sulfur, nitrogen) and the energy of its bond with oxygen.

KW - Klaus reaction

KW - Mechanism of catalytic redox reactions

KW - Methanol synthesis

KW - Selective reduction of nitrogen oxides by hydrocarbons

KW - Strongly bound intermediates

UR - http://www.scopus.com/inward/record.url?scp=0037528746&partnerID=8YFLogxK

U2 - 10.1007/BF02475810

DO - 10.1007/BF02475810

M3 - Article

AN - SCOPUS:0037528746

SN - 0133-1736

VL - 66

SP - 337

EP - 341

JO - Reaction Kinetics and Catalysis Letters

JF - Reaction Kinetics and Catalysis Letters

IS - 2

ER -

On the nature of factors determining reactivity of strongly bound surface species as intermediates in heterogeneous catalytic redox reactions

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