TY - GEN
T1 - Ordered macroporous photonic crystal hot electron plasmonic photocatalysts
AU - Collins, Gillian
AU - Lonergan, Alex
AU - McNulty, David
AU - Glynn, Colm
AU - Buckley, Darragh
AU - Hu, Changyu
AU - O'Dwyer, Colm
N1 - Publisher Copyright:
© The Electrochemical Society.
PY - 2020
Y1 - 2020
N2 - Plasmonic metal-semiconductor heterostructures are promising for photocatalytic applications since the metal and the oxide semiconductor can absorb light in the visible spectrum leading to better catalytic rates. Photon absorption efficiency can be enhanced by fashioning the catalyst into a photonic crystal that can enhance absorption at certain wavelength because of its structure. We show how Au nanoparticle sensitized V2O5 and TiO2 inverse opal photonic crystals can enhanced reaction rate for catalysis by over an order of magnitude under λ = 532 nm excitation or under white light illumination. This effect is shown to results from spectral overlap of the electronic band gap, localized surface plasmon resonance and the excitation photon energy. When we compare the photocatalytic response of Au-V2O5 IO with Au-TiO2 IO, we can selectively enhance reaction rates either in the visible or in the UV regions, depending on the bandgap of the semiconductor, and the photonic band gap of the IO. For Au-TiO2 IO, hot electron transfer occurs from the gold into the conduction band, and better catalysis under white light illumination at the TiO2 surface is attributed to improved photon adsorption in the visible by the presence of a photonic band gap, slow light in the photonic crystal to enhance photon absorption, the UV bandgap of the TiO2, and the localised surface plasmon resonance of the Au. For Au-V2O5, electron transfer to the Au in addition to enhanced absorption in the visible range, promote better catalysis at λ = 532 nm.
AB - Plasmonic metal-semiconductor heterostructures are promising for photocatalytic applications since the metal and the oxide semiconductor can absorb light in the visible spectrum leading to better catalytic rates. Photon absorption efficiency can be enhanced by fashioning the catalyst into a photonic crystal that can enhance absorption at certain wavelength because of its structure. We show how Au nanoparticle sensitized V2O5 and TiO2 inverse opal photonic crystals can enhanced reaction rate for catalysis by over an order of magnitude under λ = 532 nm excitation or under white light illumination. This effect is shown to results from spectral overlap of the electronic band gap, localized surface plasmon resonance and the excitation photon energy. When we compare the photocatalytic response of Au-V2O5 IO with Au-TiO2 IO, we can selectively enhance reaction rates either in the visible or in the UV regions, depending on the bandgap of the semiconductor, and the photonic band gap of the IO. For Au-TiO2 IO, hot electron transfer occurs from the gold into the conduction band, and better catalysis under white light illumination at the TiO2 surface is attributed to improved photon adsorption in the visible by the presence of a photonic band gap, slow light in the photonic crystal to enhance photon absorption, the UV bandgap of the TiO2, and the localised surface plasmon resonance of the Au. For Au-V2O5, electron transfer to the Au in addition to enhanced absorption in the visible range, promote better catalysis at λ = 532 nm.
UR - http://www.scopus.com/inward/record.url?scp=85092910661&partnerID=8YFLogxK
U2 - 10.1149/09802.0053ecst
DO - 10.1149/09802.0053ecst
M3 - Conference contribution
AN - SCOPUS:85092910661
T3 - ECS Transactions
SP - 53
EP - 62
BT - PRiME 2020
A2 - Granitzer, P.
A2 - Lockwood, D.
A2 - Habazaki, H.
A2 - Virtanen, S.
A2 - Imahori, H.
PB - IOP Publishing Ltd
T2 - Pacific Rim Meeting on Electrochemical and Solid State Science 2020, PRiME 200
Y2 - 4 October 2020 through 9 October 2020
ER -