Ordered macroporous photonic crystal hot electron plasmonic photocatalysts

Gillian Collins, Alex Lonergan, David McNulty, Colm Glynn, Darragh Buckley, Changyu Hu, Colm O'Dwyer

Research output: Chapter in Book/Report/Conference proceedingConference contributionpeer-review

Abstract

Plasmonic metal-semiconductor heterostructures are promising for photocatalytic applications since the metal and the oxide semiconductor can absorb light in the visible spectrum leading to better catalytic rates. Photon absorption efficiency can be enhanced by fashioning the catalyst into a photonic crystal that can enhance absorption at certain wavelength because of its structure. We show how Au nanoparticle sensitized V2O5 and TiO2 inverse opal photonic crystals can enhanced reaction rate for catalysis by over an order of magnitude under λ = 532 nm excitation or under white light illumination. This effect is shown to results from spectral overlap of the electronic band gap, localized surface plasmon resonance and the excitation photon energy. When we compare the photocatalytic response of Au-V2O5 IO with Au-TiO2 IO, we can selectively enhance reaction rates either in the visible or in the UV regions, depending on the bandgap of the semiconductor, and the photonic band gap of the IO. For Au-TiO2 IO, hot electron transfer occurs from the gold into the conduction band, and better catalysis under white light illumination at the TiO2 surface is attributed to improved photon adsorption in the visible by the presence of a photonic band gap, slow light in the photonic crystal to enhance photon absorption, the UV bandgap of the TiO2, and the localised surface plasmon resonance of the Au. For Au-V2O5, electron transfer to the Au in addition to enhanced absorption in the visible range, promote better catalysis at λ = 532 nm.

Original languageEnglish
Title of host publicationPRiME 2020
Subtitle of host publicationPits and Pores 9: Nanomaterials - Fabrication, Properties, and Applications
EditorsP. Granitzer, D. Lockwood, H. Habazaki, S. Virtanen, H. Imahori
PublisherIOP Publishing Ltd
Pages53-62
Number of pages10
Edition2
ISBN (Electronic)9781607688976
DOIs
Publication statusPublished - 2020
Externally publishedYes
EventPacific Rim Meeting on Electrochemical and Solid State Science 2020, PRiME 200 - Honolulu, United States
Duration: 4 Oct 20209 Oct 2020

Publication series

NameECS Transactions
Number2
Volume98
ISSN (Print)1938-6737
ISSN (Electronic)1938-5862

Conference

ConferencePacific Rim Meeting on Electrochemical and Solid State Science 2020, PRiME 200
Country/TerritoryUnited States
CityHonolulu
Period4/10/209/10/20

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