Abstract
A TEM study has revealed, for the first time, the presence of small (∼3 nm in diameter) voids attached to T1 (Al2CuLi) precipitates present in an artificially aged Al-Cu-Li alloy (Al-2·90Cu- 1·63Li-0·29Mg-0·28Ag-0·13Zr). These voids do not form from quenched in excess vacancies but are nucleated at the T1 phase/alloy interface from excess vacancies generated during oxidation of the TEM sample. It is concluded that these voids result from the Kirkendall effect with rapid oxidation of the TEM metal surface occurring by molecular oxygen migration through a highly defective surface oxide layer.
Original language | English |
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Pages (from-to) | 783-788 |
Number of pages | 6 |
Journal | Materials Science and Technology (United Kingdom) |
Volume | 27 |
Issue number | 4 |
DOIs | |
Publication status | Published - Apr 2011 |
Keywords
- Diffusion
- Kirkendall effect
- Thin films
- Transmission electron microscopy
- Vacancies