TY - JOUR
T1 - Oxidative addition of an alcohol to the alkylgermanium(II) compound Ge[CH(SiMe3)2]2; molecular structure of Ge[CH(SiMe3)2]2(H)OEt
AU - Lappert, Michael F.
AU - Miles, Stuart J.
AU - Atwood, Jerry L.
AU - Zaworotko, Michael J.
AU - Carty, Arthur J.
PY - 1981/5/26
Y1 - 1981/5/26
N2 - The alkylgermanium(II) compound GeR2 (R = CH(SiMe3)2) readily reacts with an alcohol R′OH (R′ = Me or Et) to yield the oxidative adduct GeR2 · R′OH, one of which (R′ = Et) has been characterised by single crystal X-ray diffraction as Ge(H)R2(OR′): GeO 1.797(5) Å GeC 1.969(6) and 1.953(7) Å, GeH 1.46(6) Å, angle HGeO 98(2)°, angle HGeC 108(2) and 120(2)°, angle CGeO 105.9(3) and 108.7(3)°.
AB - The alkylgermanium(II) compound GeR2 (R = CH(SiMe3)2) readily reacts with an alcohol R′OH (R′ = Me or Et) to yield the oxidative adduct GeR2 · R′OH, one of which (R′ = Et) has been characterised by single crystal X-ray diffraction as Ge(H)R2(OR′): GeO 1.797(5) Å GeC 1.969(6) and 1.953(7) Å, GeH 1.46(6) Å, angle HGeO 98(2)°, angle HGeC 108(2) and 120(2)°, angle CGeO 105.9(3) and 108.7(3)°.
UR - http://www.scopus.com/inward/record.url?scp=0001943833&partnerID=8YFLogxK
U2 - 10.1016/S0022-328X(00)85535-7
DO - 10.1016/S0022-328X(00)85535-7
M3 - Article
AN - SCOPUS:0001943833
SN - 0022-328X
VL - 212
SP - C4-C6
JO - Journal of Organometallic Chemistry
JF - Journal of Organometallic Chemistry
IS - 1
ER -