Oxidative addition of an alcohol to the alkylgermanium(II) compound Ge[CH(SiMe3)2]2; molecular structure of Ge[CH(SiMe3)2]2(H)OEt

Michael F. Lappert; Stuart J. Miles; Jerry L. Atwood; Michael J. Zaworotko; Arthur J. Carty

doi:10.1016/S0022-328X(00)85535-7

Oxidative addition of an alcohol to the alkylgermanium(II) compound Ge[CH(SiMe₃)₂]₂; molecular structure of Ge[CH(SiMe₃)₂]₂(H)OEt

Michael F. Lappert
, Stuart J. Miles
, Jerry L. Atwood
, Michael J. Zaworotko
, Arthur J. Carty

Research output: Contribution to journal › Article › peer-review

Abstract

The alkylgermanium(II) compound GeR₂ (R = CH(SiMe₃)₂) readily reacts with an alcohol R′OH (R′ = Me or Et) to yield the oxidative adduct GeR₂ · R′OH, one of which (R′ = Et) has been characterised by single crystal X-ray diffraction as Ge(H)R₂(OR′): GeO 1.797(5) Å GeC 1.969(6) and 1.953(7) Å, GeH 1.46(6) Å, angle HGeO 98(2)°, angle HGeC 108(2) and 120(2)°, angle CGeO 105.9(3) and 108.7(3)°.

Original language	English
Pages (from-to)	C4-C6
Journal	Journal of Organometallic Chemistry
Volume	212
Issue number	1
DOIs	https://doi.org/10.1016/S0022-328X(00)85535-7
Publication status	Published - 26 May 1981
Externally published	Yes

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@article{9ff95229dc974e8280d8acf593f3623e,

title = "Oxidative addition of an alcohol to the alkylgermanium(II) compound Ge[CH(SiMe3)2]2; molecular structure of Ge[CH(SiMe3)2]2(H)OEt",

abstract = "The alkylgermanium(II) compound GeR2 (R = CH(SiMe3)2) readily reacts with an alcohol R′OH (R′ = Me or Et) to yield the oxidative adduct GeR2 · R′OH, one of which (R′ = Et) has been characterised by single crystal X-ray diffraction as Ge(H)R2(OR′): GeO 1.797(5) {\AA} GeC 1.969(6) and 1.953(7) {\AA}, GeH 1.46(6) {\AA}, angle HGeO 98(2)°, angle HGeC 108(2) and 120(2)°, angle CGeO 105.9(3) and 108.7(3)°.",

author = "Lappert, \{Michael F.\} and Miles, \{Stuart J.\} and Atwood, \{Jerry L.\} and Zaworotko, \{Michael J.\} and Carty, \{Arthur J.\}",

year = "1981",

month = may,

day = "26",

doi = "10.1016/S0022-328X(00)85535-7",

language = "English",

volume = "212",

pages = "C4--C6",

journal = "Journal of Organometallic Chemistry",

issn = "0022-328X",

number = "1",

}

TY - JOUR

T1 - Oxidative addition of an alcohol to the alkylgermanium(II) compound Ge[CH(SiMe3)2]2; molecular structure of Ge[CH(SiMe3)2]2(H)OEt

AU - Lappert, Michael F.

AU - Miles, Stuart J.

AU - Atwood, Jerry L.

AU - Zaworotko, Michael J.

AU - Carty, Arthur J.

PY - 1981/5/26

Y1 - 1981/5/26

N2 - The alkylgermanium(II) compound GeR2 (R = CH(SiMe3)2) readily reacts with an alcohol R′OH (R′ = Me or Et) to yield the oxidative adduct GeR2 · R′OH, one of which (R′ = Et) has been characterised by single crystal X-ray diffraction as Ge(H)R2(OR′): GeO 1.797(5) Å GeC 1.969(6) and 1.953(7) Å, GeH 1.46(6) Å, angle HGeO 98(2)°, angle HGeC 108(2) and 120(2)°, angle CGeO 105.9(3) and 108.7(3)°.

AB - The alkylgermanium(II) compound GeR2 (R = CH(SiMe3)2) readily reacts with an alcohol R′OH (R′ = Me or Et) to yield the oxidative adduct GeR2 · R′OH, one of which (R′ = Et) has been characterised by single crystal X-ray diffraction as Ge(H)R2(OR′): GeO 1.797(5) Å GeC 1.969(6) and 1.953(7) Å, GeH 1.46(6) Å, angle HGeO 98(2)°, angle HGeC 108(2) and 120(2)°, angle CGeO 105.9(3) and 108.7(3)°.

UR - https://www.scopus.com/pages/publications/0001943833

U2 - 10.1016/S0022-328X(00)85535-7

DO - 10.1016/S0022-328X(00)85535-7

M3 - Article

AN - SCOPUS:0001943833

SN - 0022-328X

VL - 212

SP - C4-C6

JO - Journal of Organometallic Chemistry

JF - Journal of Organometallic Chemistry

IS - 1

ER -

Oxidative addition of an alcohol to the alkylgermanium(II) compound Ge[CH(SiMe₃)₂]₂; molecular structure of Ge[CH(SiMe₃)₂]₂(H)OEt

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