TY - JOUR
T1 - Pillar substitution modulates CO2 affinity in “mmo” topology networks
AU - Mohamed, Mona H.
AU - Elsaidi, Sameh K.
AU - Pham, Tony
AU - Forrest, Katherine A.
AU - Tudor, Brant
AU - Wojtas, Lukasz
AU - Space, Brian
AU - Zaworotko, Michael J.
PY - 2013/9/26
Y1 - 2013/9/26
N2 - The use of WO42− instead of CrO42− or MoO42− as an angular pillar in mmo topology nets has afforded two isostructural porous nets of formula [M(bpe)2WO4] (M = Co or Ni, bpe = 1,2-(4-pyridyl)ethene). The Ni variant, WOFOUR-1-Ni, is highly selective towards CO2 thanks to its exceptionally high isosteric heat of adsorption (Q st) of −65.5 kJ mol−1 at zero loading.
AB - The use of WO42− instead of CrO42− or MoO42− as an angular pillar in mmo topology nets has afforded two isostructural porous nets of formula [M(bpe)2WO4] (M = Co or Ni, bpe = 1,2-(4-pyridyl)ethene). The Ni variant, WOFOUR-1-Ni, is highly selective towards CO2 thanks to its exceptionally high isosteric heat of adsorption (Q st) of −65.5 kJ mol−1 at zero loading.
UR - http://www.scopus.com/inward/record.url?scp=84884843255&partnerID=8YFLogxK
U2 - 10.1039/c3cc44745f
DO - 10.1039/c3cc44745f
M3 - Article
AN - SCOPUS:84884843255
SN - 1359-7345
VL - 49
SP - 9809
EP - 9811
JO - Chemical Communications
JF - Chemical Communications
IS - 84
ER -