Porous Nb2O5 Nanofibers Prepared via Reactive Needle-Less Electrospinning for Application in Lithium–Sulfur Batteries

Ivan Shepa, Erika Mudra, Dominika Capkova, Alexandra Kovalcikova, Ondrej Petrus, Frantisek Kromka, Ondrej Milkovic, Vitaliy Antal, Matej Balaz, Maksym Lisnichuk, Dominika Marcin-Behunova, Dóra Zalka, Jan Dusza

Research output: Contribution to journalArticlepeer-review

Abstract

This contribution describes the preparation, coupled with detailed characterization, of Nb2O5 nanofibers and their application in lithium–sulfur batteries for the improvement of electrochemical performance. The utilization of reactive needle-less electrospinning allowed us to obtain, in a single step, amorphous pre-ceramic composite PAN/Nb2O5 fibers, which were transformed into porous ceramic Nb2O5 nanofibers via calcination. Thermogravimetric studies defined that calcination at 600 °C results in crystalline ceramic fibers without carbon residues. The fibrous morphology and mean diameter (614 ± 100 nm) of the ceramic nanofibers were analyzed via scanning and transmission electron microscopy. A surface area of 7.472 m2/g was determined through nitrogen adsorption measurements, while a combination of X-ray diffraction and Raman spectroscopy was used to show the crystallinity and composition of the fibers after calcination—single T-phase Nb2O5. Its performance in the cathode of lithium–sulfur batteries was defined through electrochemical tests, and the obtained results were compared to a similar blank electrode. The initial discharge capacity of 0.5 C reached a value of 570 mAh∙g−1, while the reversible capacity of 406 mAh∙g−1 was retained after 200 cycles, representing a capacity retention of 71.3%. The presence of Nb2O5 nanofibers in the carbon cathode inhibits the shuttle effect through polysulphide confinement, which originates from porosity and chemical trapping.

Original languageEnglish
Article number456
JournalInorganics
Volume11
Issue number12
DOIs
Publication statusPublished - Dec 2023

Keywords

  • lithium–sulfur batteries
  • nanofibers
  • needle-less electrospinning
  • niobia
  • oxide ceramics

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