Porous noria polymer: a cage-to-network approach toward a robust catalyst for CO2fixation and nitroarene reduction

Arkaprabha Giri; Niraj Nitish Patil; Abhijit Patra

doi:10.1039/d0cc07805k

Porous noria polymer: a cage-to-network approach toward a robust catalyst for CO₂fixation and nitroarene reduction

Arkaprabha Giri, Niraj Nitish Patil, Abhijit Patra

Indian Institute of Science Education and Research Bhopal

Research output: Contribution to journal › Article › peer-review

Abstract

The advantages of the cage-to-network design strategy were demonstrated by knitting a waterwheel-like preporous molecular cage, noria, with a rigid aromatic linker to obtain a highly microporous organic polymer (NPOP,S_BET: 748 ± 25 m²g⁻¹). The NPOP was employed for the catalytic conversion of CO₂to cyclic carbonates under solvent-free reaction conditions. Furthermore, a silver nanoparticle encapsulated NPOP exhibited remarkable catalytic activity for nitroarene reduction with excellent recyclability.

Original language	English
Pages (from-to)	4404-4407
Number of pages	4
Journal	Chemical Communications
Volume	57
Issue number	36
DOIs	https://doi.org/10.1039/d0cc07805k
Publication status	Published - 4 May 2021
Externally published	Yes

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title = "Porous noria polymer: a cage-to-network approach toward a robust catalyst for CO2fixation and nitroarene reduction",

abstract = "The advantages of the cage-to-network design strategy were demonstrated by knitting a waterwheel-like preporous molecular cage, noria, with a rigid aromatic linker to obtain a highly microporous organic polymer (NPOP,SBET: 748 ± 25 m2g−1). The NPOP was employed for the catalytic conversion of CO2to cyclic carbonates under solvent-free reaction conditions. Furthermore, a silver nanoparticle encapsulated NPOP exhibited remarkable catalytic activity for nitroarene reduction with excellent recyclability.",

author = "Arkaprabha Giri and Patil, \{Niraj Nitish\} and Abhijit Patra",

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AU - Patil, Niraj Nitish

AU - Patra, Abhijit

N1 - Publisher Copyright: © The Royal Society of Chemistry 2021.

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Y1 - 2021/5/4

N2 - The advantages of the cage-to-network design strategy were demonstrated by knitting a waterwheel-like preporous molecular cage, noria, with a rigid aromatic linker to obtain a highly microporous organic polymer (NPOP,SBET: 748 ± 25 m2g−1). The NPOP was employed for the catalytic conversion of CO2to cyclic carbonates under solvent-free reaction conditions. Furthermore, a silver nanoparticle encapsulated NPOP exhibited remarkable catalytic activity for nitroarene reduction with excellent recyclability.

AB - The advantages of the cage-to-network design strategy were demonstrated by knitting a waterwheel-like preporous molecular cage, noria, with a rigid aromatic linker to obtain a highly microporous organic polymer (NPOP,SBET: 748 ± 25 m2g−1). The NPOP was employed for the catalytic conversion of CO2to cyclic carbonates under solvent-free reaction conditions. Furthermore, a silver nanoparticle encapsulated NPOP exhibited remarkable catalytic activity for nitroarene reduction with excellent recyclability.

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U2 - 10.1039/d0cc07805k

DO - 10.1039/d0cc07805k

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JO - Chemical Communications

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ER -

Porous noria polymer: a cage-to-network approach toward a robust catalyst for CO₂fixation and nitroarene reduction

Abstract

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