Possible intermediates in the selective catalytic reduction of NOx: Differences in the reactivity of nitro-compounds and tert-butyl nitrite over γ-Al2O3

Virginie Zuzaniuk; Frederic C. Meunier; Julian R.H. Ross

doi:10.1039/a900548j

Possible intermediates in the selective catalytic reduction of NO_x: Differences in the reactivity of nitro-compounds and tert-butyl nitrite over γ-Al₂O₃

Virginie Zuzaniuk, Frederic C. Meunier, Julian R.H. Ross

Retired Staff

Research output: Contribution to journal › Article › peer-review

Abstract

Nitromethane decomposes over alumina to give various surface species such as isocyanates and its oxidation by O₂ yields significant amounts of ammonia; on the other hand, tert-butyl nitrite decomposes to give only surface nitrate species and mostly oxides of nitrogen are formed by reaction with O₂.

Original language	English
Pages (from-to)	815-816
Number of pages	2
Journal	Chemical Communications
Issue number	9
DOIs	https://doi.org/10.1039/a900548j
Publication status	Published - 7 May 1999

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title = "Possible intermediates in the selective catalytic reduction of NOx: Differences in the reactivity of nitro-compounds and tert-butyl nitrite over γ-Al2O3",

abstract = "Nitromethane decomposes over alumina to give various surface species such as isocyanates and its oxidation by O2 yields significant amounts of ammonia; on the other hand, tert-butyl nitrite decomposes to give only surface nitrate species and mostly oxides of nitrogen are formed by reaction with O2.",

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AU - Ross, Julian R.H.

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AB - Nitromethane decomposes over alumina to give various surface species such as isocyanates and its oxidation by O2 yields significant amounts of ammonia; on the other hand, tert-butyl nitrite decomposes to give only surface nitrate species and mostly oxides of nitrogen are formed by reaction with O2.

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Possible intermediates in the selective catalytic reduction of NO_x: Differences in the reactivity of nitro-compounds and tert-butyl nitrite over γ-Al₂O₃

Abstract

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