Post-synthetic modification of porphyrin-encapsulating metal-organic materials by cooperative addition of inorganic salts to enhance CO 2/CH 4 selectivity

Zhenjie Zhang; Wen Yang Gao; Lukasz Wojtas; Shengqian Ma; Mohamed Eddaoudi; Michael J. Zaworotko

doi:10.1002/anie.201203594

Post-synthetic modification of porphyrin-encapsulating metal-organic materials by cooperative addition of inorganic salts to enhance CO ₂/CH ₄ selectivity

Zhenjie Zhang, Wen Yang Gao, Lukasz Wojtas, Shengqian Ma, Mohamed Eddaoudi, Michael J. Zaworotko

Research output: Contribution to journal › Article › peer-review

Abstract

Keeping MOM: Reaction of biphenyl-3,4',5-tricarboxylate and Cd(NO ₃) ₂ in the presence of meso-tetra(N-methyl-4-pyridyl) porphine tetratosylate afforded porph@MOM-11, a microporous metal-organic material (MOM) that encapsulates cationic porphyrins and solvent in alternating open channels. Porph@MOM-11 has cation and anion binding sites that facilitate cooperative addition of inorganic salts (such as M ⁺Cl ^-) in a stoichiometric fashion.

Original language	English
Pages (from-to)	9330-9334
Number of pages	5
Journal	Angewandte Chemie - International Edition
Volume	51
Issue number	37
DOIs	https://doi.org/10.1002/anie.201203594
Publication status	Published - 10 Sep 2012
Externally published	Yes

Keywords

CO /CH selectivity
encapsulation
metal salts
metal-organic frameworks
porphyrinoids

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10.1002/anie.201203594

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title = "Post-synthetic modification of porphyrin-encapsulating metal-organic materials by cooperative addition of inorganic salts to enhance CO 2/CH 4 selectivity",

abstract = "Keeping MOM: Reaction of biphenyl-3,4',5-tricarboxylate and Cd(NO 3) 2 in the presence of meso-tetra(N-methyl-4-pyridyl) porphine tetratosylate afforded porph@MOM-11, a microporous metal-organic material (MOM) that encapsulates cationic porphyrins and solvent in alternating open channels. Porph@MOM-11 has cation and anion binding sites that facilitate cooperative addition of inorganic salts (such as M +Cl -) in a stoichiometric fashion.",

keywords = "CO /CH selectivity, encapsulation, metal salts, metal-organic frameworks, porphyrinoids",

author = "Zhenjie Zhang and Gao, {Wen Yang} and Lukasz Wojtas and Shengqian Ma and Mohamed Eddaoudi and Zaworotko, {Michael J.}",

year = "2012",

month = sep,

day = "10",

doi = "10.1002/anie.201203594",

language = "English",

volume = "51",

pages = "9330--9334",

journal = "Angewandte Chemie - International Edition",

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T1 - Post-synthetic modification of porphyrin-encapsulating metal-organic materials by cooperative addition of inorganic salts to enhance CO 2/CH 4 selectivity

AU - Zhang, Zhenjie

AU - Gao, Wen Yang

AU - Wojtas, Lukasz

AU - Ma, Shengqian

AU - Eddaoudi, Mohamed

AU - Zaworotko, Michael J.

PY - 2012/9/10

Y1 - 2012/9/10

N2 - Keeping MOM: Reaction of biphenyl-3,4',5-tricarboxylate and Cd(NO 3) 2 in the presence of meso-tetra(N-methyl-4-pyridyl) porphine tetratosylate afforded porph@MOM-11, a microporous metal-organic material (MOM) that encapsulates cationic porphyrins and solvent in alternating open channels. Porph@MOM-11 has cation and anion binding sites that facilitate cooperative addition of inorganic salts (such as M +Cl -) in a stoichiometric fashion.

AB - Keeping MOM: Reaction of biphenyl-3,4',5-tricarboxylate and Cd(NO 3) 2 in the presence of meso-tetra(N-methyl-4-pyridyl) porphine tetratosylate afforded porph@MOM-11, a microporous metal-organic material (MOM) that encapsulates cationic porphyrins and solvent in alternating open channels. Porph@MOM-11 has cation and anion binding sites that facilitate cooperative addition of inorganic salts (such as M +Cl -) in a stoichiometric fashion.

KW - CO /CH selectivity

KW - encapsulation

KW - metal salts

KW - metal-organic frameworks

KW - porphyrinoids

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U2 - 10.1002/anie.201203594

DO - 10.1002/anie.201203594

M3 - Article

AN - SCOPUS:84865856859

SN - 1433-7851

VL - 51

SP - 9330

EP - 9334

JO - Angewandte Chemie - International Edition

JF - Angewandte Chemie - International Edition

IS - 37

ER -

Post-synthetic modification of porphyrin-encapsulating metal-organic materials by cooperative addition of inorganic salts to enhance CO ₂/CH ₄ selectivity

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Keywords

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