TY - JOUR
T1 - Post-synthetic modifications of cadmium-based knots and links
AU - Prakasam, Thirumurugan
AU - Bilbeisi, Rana A.
AU - Lusi, Matteo
AU - Olsen, John Carl
AU - Platas-Iglesias, Carlos
AU - Trabolsi, Ali
N1 - Publisher Copyright:
© The Royal Society of Chemistry 2016.
PY - 2016
Y1 - 2016
N2 - Three topologically non-trivial cadmium(ii)-based complexes - Cd-[2]C, Cd-TK and Cd-SL - were simultaneously self-assembled in a dynamic library, individually isolated and fully characterized using solid-state, gas-phase and solution-phase techniques. Post-synthetic modifications, including reduction and transmetalation, were subsequently achieved. Imine bond reduction followed by demetallation led to the isolation of the corresponding organic molecules [2]C, TK and SL. Transmetalation of Cd-TK and Cd-SL with the zinc(ii) cation resulted in isolation of the corresponding zinc(ii)-containing complexes Zn-TK and Zn-SL.
AB - Three topologically non-trivial cadmium(ii)-based complexes - Cd-[2]C, Cd-TK and Cd-SL - were simultaneously self-assembled in a dynamic library, individually isolated and fully characterized using solid-state, gas-phase and solution-phase techniques. Post-synthetic modifications, including reduction and transmetalation, were subsequently achieved. Imine bond reduction followed by demetallation led to the isolation of the corresponding organic molecules [2]C, TK and SL. Transmetalation of Cd-TK and Cd-SL with the zinc(ii) cation resulted in isolation of the corresponding zinc(ii)-containing complexes Zn-TK and Zn-SL.
UR - http://www.scopus.com/inward/record.url?scp=84973307759&partnerID=8YFLogxK
U2 - 10.1039/c6cc02423h
DO - 10.1039/c6cc02423h
M3 - Article
AN - SCOPUS:84973307759
SN - 1359-7345
VL - 52
SP - 7398
EP - 7401
JO - Chemical Communications
JF - Chemical Communications
IS - 46
ER -