Post-synthetic transformation of a Zn(II) polyhedral coordination network into a new supramolecular isomer of HKUST-1

Yao Chen; Lukasz Wojtas; Shengqian Ma; Michael J. Zaworotko; Zhenjie Zhang

doi:10.1039/c7cc04958g

Post-synthetic transformation of a Zn(II) polyhedral coordination network into a new supramolecular isomer of HKUST-1

Yao Chen, Lukasz Wojtas, Shengqian Ma, Michael J. Zaworotko, Zhenjie Zhang

Department of Chemical Sciences

Research output: Contribution to journal › Article › peer-review

Abstract

A Zn-based porphyrin containing metal-organic material (porphMOM-1) was transformed into a novel Cu-based porphyrin-encapsulating metal-organic material (porph@HKUST-1-β) via a one-pot post-synthetic modification (PSM) process involving both metal ion exchange and linker installation of trimesic acid. HKUST-1-β is the first example of yao topology and is to our knowledge the first supramolecular isomer of the archetypal coordination network HKUST-1.

Original language	English
Pages (from-to)	8866-8869
Number of pages	4
Journal	Chemical Communications
Volume	53
Issue number	63
DOIs	https://doi.org/10.1039/c7cc04958g
Publication status	Published - 2017

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title = "Post-synthetic transformation of a Zn(II) polyhedral coordination network into a new supramolecular isomer of HKUST-1",

abstract = "A Zn-based porphyrin containing metal-organic material (porphMOM-1) was transformed into a novel Cu-based porphyrin-encapsulating metal-organic material (porph@HKUST-1-β) via a one-pot post-synthetic modification (PSM) process involving both metal ion exchange and linker installation of trimesic acid. HKUST-1-β is the first example of yao topology and is to our knowledge the first supramolecular isomer of the archetypal coordination network HKUST-1.",

author = "Yao Chen and Lukasz Wojtas and Shengqian Ma and Zaworotko, {Michael J.} and Zhenjie Zhang",

note = "Publisher Copyright: {\textcopyright} 2017 The Royal Society of Chemistry.",

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AU - Chen, Yao

AU - Wojtas, Lukasz

AU - Ma, Shengqian

AU - Zaworotko, Michael J.

AU - Zhang, Zhenjie

PY - 2017

Y1 - 2017

N2 - A Zn-based porphyrin containing metal-organic material (porphMOM-1) was transformed into a novel Cu-based porphyrin-encapsulating metal-organic material (porph@HKUST-1-β) via a one-pot post-synthetic modification (PSM) process involving both metal ion exchange and linker installation of trimesic acid. HKUST-1-β is the first example of yao topology and is to our knowledge the first supramolecular isomer of the archetypal coordination network HKUST-1.

AB - A Zn-based porphyrin containing metal-organic material (porphMOM-1) was transformed into a novel Cu-based porphyrin-encapsulating metal-organic material (porph@HKUST-1-β) via a one-pot post-synthetic modification (PSM) process involving both metal ion exchange and linker installation of trimesic acid. HKUST-1-β is the first example of yao topology and is to our knowledge the first supramolecular isomer of the archetypal coordination network HKUST-1.

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EP - 8869

JO - Chemical Communications

JF - Chemical Communications

IS - 63

ER -

Post-synthetic transformation of a Zn(II) polyhedral coordination network into a new supramolecular isomer of HKUST-1

Abstract

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