Preparation and characterization of 1-butyl-3-methylimidazolium tetrakis(3,5-bis(trifluoromethyl) phenyl)borate, [bmim]BARF

Jeremy Finden; Gavin Beck; Andrea Lantz; Rosa Walsh; Michael J. Zaworotko; Robert D. Singer

doi:10.1023/A:1023885212233

Preparation and characterization of 1-butyl-3-methylimidazolium tetrakis(3,5-bis(trifluoromethyl) phenyl)borate, [bmim]BARF

Jeremy Finden, Gavin Beck, Andrea Lantz, Rosa Walsh, Michael J. Zaworotko, Robert D. Singer

Research output: Contribution to journal › Article › peer-review

Abstract

Attempts to prepare novel air and moisture stable room-temperature ionic liquids have afforded a new 1,3-dialkylimidazolium tetraarylborate salt: 1-butyl-3-methylimidazolium tetrakis(3,5-bis(trifluoromethyl)phenyl)borate, [bmim]BARF, 1. Crystal data: C₈₀H₅₄B₂F ₄₈N₄, monoclinic space group P2(1)/n, a = 21.2622(17) Å, b = 15.8037(13) Å, c = 26.227(2) Å, β= 101.841(2) Å³, V = 8625.3(12) Å³, Z = 1.544.

Original language	English
Pages (from-to)	287-295
Number of pages	9
Journal	Journal of Chemical Crystallography
Volume	33
Issue number	4
DOIs	https://doi.org/10.1023/A:1023885212233
Publication status	Published - Apr 2003
Externally published	Yes

Keywords

BARF
Crystal structure
Ionic liquid
Moisture stable

Access to Document

10.1023/A:1023885212233

Cite this

@article{bf60eadd3de74fc0aab5913978d53674,

title = "Preparation and characterization of 1-butyl-3-methylimidazolium tetrakis(3,5-bis(trifluoromethyl) phenyl)borate, [bmim]BARF",

abstract = "Attempts to prepare novel air and moisture stable room-temperature ionic liquids have afforded a new 1,3-dialkylimidazolium tetraarylborate salt: 1-butyl-3-methylimidazolium tetrakis(3,5-bis(trifluoromethyl)phenyl)borate, [bmim]BARF, 1. Crystal data: C80H54B2F 48N4, monoclinic space group P2(1)/n, a = 21.2622(17) {\AA}, b = 15.8037(13) {\AA}, c = 26.227(2) {\AA}, β= 101.841(2) {\AA}3, V = 8625.3(12) {\AA}3, Z = 1.544.",

keywords = "BARF, Crystal structure, Ionic liquid, Moisture stable",

author = "Jeremy Finden and Gavin Beck and Andrea Lantz and Rosa Walsh and Zaworotko, {Michael J.} and Singer, {Robert D.}",

year = "2003",

month = apr,

doi = "10.1023/A:1023885212233",

language = "English",

volume = "33",

pages = "287--295",

journal = "Journal of Chemical Crystallography",

issn = "1074-1542",

number = "4",

}

TY - JOUR

T1 - Preparation and characterization of 1-butyl-3-methylimidazolium tetrakis(3,5-bis(trifluoromethyl) phenyl)borate, [bmim]BARF

AU - Finden, Jeremy

AU - Beck, Gavin

AU - Lantz, Andrea

AU - Walsh, Rosa

AU - Zaworotko, Michael J.

AU - Singer, Robert D.

PY - 2003/4

Y1 - 2003/4

N2 - Attempts to prepare novel air and moisture stable room-temperature ionic liquids have afforded a new 1,3-dialkylimidazolium tetraarylborate salt: 1-butyl-3-methylimidazolium tetrakis(3,5-bis(trifluoromethyl)phenyl)borate, [bmim]BARF, 1. Crystal data: C80H54B2F 48N4, monoclinic space group P2(1)/n, a = 21.2622(17) Å, b = 15.8037(13) Å, c = 26.227(2) Å, β= 101.841(2) Å3, V = 8625.3(12) Å3, Z = 1.544.

AB - Attempts to prepare novel air and moisture stable room-temperature ionic liquids have afforded a new 1,3-dialkylimidazolium tetraarylborate salt: 1-butyl-3-methylimidazolium tetrakis(3,5-bis(trifluoromethyl)phenyl)borate, [bmim]BARF, 1. Crystal data: C80H54B2F 48N4, monoclinic space group P2(1)/n, a = 21.2622(17) Å, b = 15.8037(13) Å, c = 26.227(2) Å, β= 101.841(2) Å3, V = 8625.3(12) Å3, Z = 1.544.

KW - BARF

KW - Crystal structure

KW - Ionic liquid

KW - Moisture stable

UR - http://www.scopus.com/inward/record.url?scp=0038323177&partnerID=8YFLogxK

U2 - 10.1023/A:1023885212233

DO - 10.1023/A:1023885212233

M3 - Article

AN - SCOPUS:0038323177

SN - 1074-1542

VL - 33

SP - 287

EP - 295

JO - Journal of Chemical Crystallography

JF - Journal of Chemical Crystallography

IS - 4

ER -

Preparation and characterization of 1-butyl-3-methylimidazolium tetrakis(3,5-bis(trifluoromethyl) phenyl)borate, [bmim]BARF

Abstract

Keywords

Access to Document

Other files and links

Fingerprint

Cite this