Preparation of polymer networks for hydrogen storage using the Ullmann synthetic protocol

K. A. Shaffei; Ayman M. Atta; Clara S.B. Gomes; Pedro T. Gomes; R. A. El-Ghazawy; Abdallah G. Mahmoud

doi:10.1007/s10965-014-0445-0

Preparation of polymer networks for hydrogen storage using the Ullmann synthetic protocol

K. A. Shaffei
, Ayman M. Atta
, Clara S.B. Gomes
, Pedro T. Gomes
, R. A. El-Ghazawy
, Abdallah G. Mahmoud

Helwan University
King Saud University
Egyptian Petroleum Research Institute
University of Lisbon
Departamento de Engenharia Química

Research output: Contribution to journal › Article › peer-review

Abstract

Based on the Ullmann synthetic protocol, melamine-based porous organic networks, to be used for hydrogen storage, were prepared by a facile one-pot approach. These polymers were produced by condensation of melamine with different aryl halides under mild conditions, using a soluble copper(I) complex as catalyst. These materials exhibit Brunauer-Emmett-Teller (BET) surface areas up to 19.8 m²/g as measured by N₂ adsorption at 77 K, and exhibit gravimetric storage capacities up to 1.17 wt.%, at 20 bar and 77 K.

Original language	English
Article number	445
Journal	Journal of Polymer Research
Volume	21
Issue number	5
DOIs	https://doi.org/10.1007/s10965-014-0445-0
Publication status	Published - May 2014
Externally published	Yes

UN SDGs

This output contributes to the following UN Sustainable Development Goals (SDGs)

SDG 7 Affordable and Clean Energy

Keywords

Hydrogen storage
Organic networks
Porous polymers
Ullmann coupling

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10.1007/s10965-014-0445-0

Cite this

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title = "Preparation of polymer networks for hydrogen storage using the Ullmann synthetic protocol",

abstract = "Based on the Ullmann synthetic protocol, melamine-based porous organic networks, to be used for hydrogen storage, were prepared by a facile one-pot approach. These polymers were produced by condensation of melamine with different aryl halides under mild conditions, using a soluble copper(I) complex as catalyst. These materials exhibit Brunauer-Emmett-Teller (BET) surface areas up to 19.8 m2/g as measured by N2 adsorption at 77 K, and exhibit gravimetric storage capacities up to 1.17 wt.\%, at 20 bar and 77 K.",

keywords = "Hydrogen storage, Organic networks, Porous polymers, Ullmann coupling",

author = "Shaffei, \{K. A.\} and Atta, \{Ayman M.\} and Gomes, \{Clara S.B.\} and Gomes, \{Pedro T.\} and El-Ghazawy, \{R. A.\} and Mahmoud, \{Abdallah G.\}",

year = "2014",

month = may,

doi = "10.1007/s10965-014-0445-0",

language = "English",

volume = "21",

journal = "Journal of Polymer Research",

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TY - JOUR

T1 - Preparation of polymer networks for hydrogen storage using the Ullmann synthetic protocol

AU - Shaffei, K. A.

AU - Atta, Ayman M.

AU - Gomes, Clara S.B.

AU - Gomes, Pedro T.

AU - El-Ghazawy, R. A.

AU - Mahmoud, Abdallah G.

PY - 2014/5

Y1 - 2014/5

N2 - Based on the Ullmann synthetic protocol, melamine-based porous organic networks, to be used for hydrogen storage, were prepared by a facile one-pot approach. These polymers were produced by condensation of melamine with different aryl halides under mild conditions, using a soluble copper(I) complex as catalyst. These materials exhibit Brunauer-Emmett-Teller (BET) surface areas up to 19.8 m2/g as measured by N2 adsorption at 77 K, and exhibit gravimetric storage capacities up to 1.17 wt.%, at 20 bar and 77 K.

AB - Based on the Ullmann synthetic protocol, melamine-based porous organic networks, to be used for hydrogen storage, were prepared by a facile one-pot approach. These polymers were produced by condensation of melamine with different aryl halides under mild conditions, using a soluble copper(I) complex as catalyst. These materials exhibit Brunauer-Emmett-Teller (BET) surface areas up to 19.8 m2/g as measured by N2 adsorption at 77 K, and exhibit gravimetric storage capacities up to 1.17 wt.%, at 20 bar and 77 K.

KW - Hydrogen storage

KW - Organic networks

KW - Porous polymers

KW - Ullmann coupling

UR - https://www.scopus.com/pages/publications/84901278352

U2 - 10.1007/s10965-014-0445-0

DO - 10.1007/s10965-014-0445-0

M3 - Article

AN - SCOPUS:84901278352

SN - 1022-9760

VL - 21

JO - Journal of Polymer Research

JF - Journal of Polymer Research

IS - 5

M1 - 445

ER -

Preparation of polymer networks for hydrogen storage using the Ullmann synthetic protocol

Abstract

UN SDGs

Keywords

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