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Pyrazolyl-Bridged Iridium Dimers. 7.1 Synthesis and Properties of Bridge-Substituted Analogues of [Ir(COD)(μ-pz)]2 (pzH = Pyrazole), the “Mixed-Bridge” Complex [Ir2(COD)2(μ-pz)(μ-fpz)] (fpzH = 3, 5-Bis(trifluoromethyl)pyrazole), and the “Mixed-Metal” Dimer [IrRh(COD)2(μ-pz)2]. Crystal and Molecular Structures of Bis(cyclooctadiene)bis(μ-3-phenyl-5-methylpyrazolyl)-diiridium(I) (Dissymmetric Isomer) and Bis(cyclooctadiene)bis(μ-3, 4, 5-trimethylpyrazolyl)diiridium(I)

  • Gordon W. Bushnell
  • , D. O. Kimberley Fjeldsted
  • , Stephen R. Stobart
  • , Michael J. Zaworotko
  • , Selby A.R. Knox
  • , Kirsty A. Macpherson
  • University of Victoria BC
  • University of Bristol

Research output: Contribution to journal › Article › peer-review

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Dive into the research topics of 'Pyrazolyl-Bridged Iridium Dimers. 7.1 Synthesis and Properties of Bridge-Substituted Analogues of [Ir(COD)(μ-pz)]2 (pzH = Pyrazole), the “Mixed-Bridge” Complex [Ir2(COD)2(μ-pz)(μ-fpz)] (fpzH = 3, 5-Bis(trifluoromethyl)pyrazole), and the “Mixed-Metal” Dimer [IrRh(COD)2(μ-pz)2]. Crystal and Molecular Structures of Bis(cyclooctadiene)bis(μ-3-phenyl-5-methylpyrazolyl)-diiridium(I) (Dissymmetric Isomer) and Bis(cyclooctadiene)bis(μ-3, 4, 5-trimethylpyrazolyl)diiridium(I)'. Together they form a unique fingerprint.
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