Recyclable switching between nonporous and porous phases of a square lattice (sql) topology coordination network

Shi Qiang Wang, Qing Yuan Yang, Soumya Mukherjee, Daniel O'Nolan, Ewa Patyk-Kaźmierczak, Kai Jie Chen, Mohana Shivanna, Claire Murray, Chiu C. Tang, Michael J. Zaworotko

Research output: Contribution to journalArticlepeer-review

Abstract

A nonporous square lattice (sql) coordination network [Co(bipy)2(NCS)2]n (sql-1-Co-NCS) exhibits recyclable switching induced by CO2. The sorption isotherms are stepped with moderate hysteresis, temperature controlled and saturation uptake is fixed. Such switching, which has rarely been observed, offers the promise of exceptional working capacity for gas storage.

Original languageEnglish
Pages (from-to)7042-7045
Number of pages4
JournalChemical Communications
Volume54
Issue number51
DOIs
Publication statusPublished - 2018

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