Remote stabilization of copper paddlewheel based molecular building blocks in metal-organic frameworks

Wen Yang Gao; Rong Cai; Tony Pham; Katherine A. Forrest; Adam Hogan; Patrick Nugent; Kia Williams; Lukasz Wojtas; Ryan Luebke; Łukasz J. Weseliński; Michael J. Zaworotko; Brian Space; Yu Sheng Chen; Mohamed Eddaoudi; Xiaodong Shi; Shengqian Ma

doi:10.1021/acs.chemmater.5b00084

Remote stabilization of copper paddlewheel based molecular building blocks in metal-organic frameworks

Wen Yang Gao, Rong Cai, Tony Pham, Katherine A. Forrest, Adam Hogan, Patrick Nugent, Kia Williams, Lukasz Wojtas, Ryan Luebke, Łukasz J. Weseliński, Michael J. Zaworotko, Brian Space, Yu Sheng Chen, Mohamed Eddaoudi, Xiaodong Shi, Shengqian Ma

Research output: Contribution to journal › Article › peer-review

Abstract

Copper paddlewheel based molecular building blocks (MBBs) are ubiquitous and have been widely employed for the construction of highly porous metal-organic frameworks (MOFs). However, most copper paddlewheel based MOFs fail to retain their structural integrity in the presence of water. This instability is directly correlated to the plausible displacement of coordinating carboxylates in the copper paddlewheel MBB, [Cu₂(O₂C-)₄], by the strongly coordinating water molecules. In this comprehensive study, we illustrate the chemical stability control in the rht-MOF platform via strengthening the coordinating bonds within the triangular inorganic MBB, [Cu₃O(N_4-x(CH)_xC-)₃] (x = 0, 1, or 2). Remotely, the chemical stabilization propagated into the paddlewheel MBB to afford isoreticular rht-MOFs with remarkably enhanced water/chemical stabilities compared to the prototypal rht-MOF-1.

Original language	English
Pages (from-to)	2144-2151
Number of pages	8
Journal	Chemistry of Materials
Volume	27
Issue number	6
DOIs	https://doi.org/10.1021/acs.chemmater.5b00084
Publication status	Published - 24 Mar 2015
Externally published	Yes

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Gao, W. Y., Cai, R., Pham, T., Forrest, K. A., Hogan, A., Nugent, P., Williams, K., Wojtas, L., Luebke, R., Weseliński, Ł. J., Zaworotko, M. J., Space, B., Chen, Y. S., Eddaoudi, M., Shi, X., & Ma, S. (2015). Remote stabilization of copper paddlewheel based molecular building blocks in metal-organic frameworks. Chemistry of Materials, 27(6), 2144-2151. https://doi.org/10.1021/acs.chemmater.5b00084

@article{d098e12833524ee49d0517965361decb,

title = "Remote stabilization of copper paddlewheel based molecular building blocks in metal-organic frameworks",

abstract = "Copper paddlewheel based molecular building blocks (MBBs) are ubiquitous and have been widely employed for the construction of highly porous metal-organic frameworks (MOFs). However, most copper paddlewheel based MOFs fail to retain their structural integrity in the presence of water. This instability is directly correlated to the plausible displacement of coordinating carboxylates in the copper paddlewheel MBB, [Cu2(O2C-)4], by the strongly coordinating water molecules. In this comprehensive study, we illustrate the chemical stability control in the rht-MOF platform via strengthening the coordinating bonds within the triangular inorganic MBB, [Cu3O(N4-x(CH)xC-)3] (x = 0, 1, or 2). Remotely, the chemical stabilization propagated into the paddlewheel MBB to afford isoreticular rht-MOFs with remarkably enhanced water/chemical stabilities compared to the prototypal rht-MOF-1.",

author = "Gao, {Wen Yang} and Rong Cai and Tony Pham and Forrest, {Katherine A.} and Adam Hogan and Patrick Nugent and Kia Williams and Lukasz Wojtas and Ryan Luebke and Weseli{\'n}ski, {{\L}ukasz J.} and Zaworotko, {Michael J.} and Brian Space and Chen, {Yu Sheng} and Mohamed Eddaoudi and Xiaodong Shi and Shengqian Ma",

note = "Publisher Copyright: {\textcopyright} 2015 American Chemical Society.",

year = "2015",

month = mar,

day = "24",

doi = "10.1021/acs.chemmater.5b00084",

language = "English",

volume = "27",

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Gao, WY, Cai, R, Pham, T, Forrest, KA, Hogan, A, Nugent, P, Williams, K, Wojtas, L, Luebke, R, Weseliński, ŁJ, Zaworotko, MJ, Space, B, Chen, YS, Eddaoudi, M, Shi, X & Ma, S 2015, 'Remote stabilization of copper paddlewheel based molecular building blocks in metal-organic frameworks', Chemistry of Materials, vol. 27, no. 6, pp. 2144-2151. https://doi.org/10.1021/acs.chemmater.5b00084

TY - JOUR

T1 - Remote stabilization of copper paddlewheel based molecular building blocks in metal-organic frameworks

AU - Gao, Wen Yang

AU - Cai, Rong

AU - Pham, Tony

AU - Forrest, Katherine A.

AU - Hogan, Adam

AU - Nugent, Patrick

AU - Williams, Kia

AU - Wojtas, Lukasz

AU - Luebke, Ryan

AU - Weseliński, Łukasz J.

AU - Zaworotko, Michael J.

AU - Space, Brian

AU - Chen, Yu Sheng

AU - Eddaoudi, Mohamed

AU - Shi, Xiaodong

AU - Ma, Shengqian

PY - 2015/3/24

Y1 - 2015/3/24

N2 - Copper paddlewheel based molecular building blocks (MBBs) are ubiquitous and have been widely employed for the construction of highly porous metal-organic frameworks (MOFs). However, most copper paddlewheel based MOFs fail to retain their structural integrity in the presence of water. This instability is directly correlated to the plausible displacement of coordinating carboxylates in the copper paddlewheel MBB, [Cu2(O2C-)4], by the strongly coordinating water molecules. In this comprehensive study, we illustrate the chemical stability control in the rht-MOF platform via strengthening the coordinating bonds within the triangular inorganic MBB, [Cu3O(N4-x(CH)xC-)3] (x = 0, 1, or 2). Remotely, the chemical stabilization propagated into the paddlewheel MBB to afford isoreticular rht-MOFs with remarkably enhanced water/chemical stabilities compared to the prototypal rht-MOF-1.

AB - Copper paddlewheel based molecular building blocks (MBBs) are ubiquitous and have been widely employed for the construction of highly porous metal-organic frameworks (MOFs). However, most copper paddlewheel based MOFs fail to retain their structural integrity in the presence of water. This instability is directly correlated to the plausible displacement of coordinating carboxylates in the copper paddlewheel MBB, [Cu2(O2C-)4], by the strongly coordinating water molecules. In this comprehensive study, we illustrate the chemical stability control in the rht-MOF platform via strengthening the coordinating bonds within the triangular inorganic MBB, [Cu3O(N4-x(CH)xC-)3] (x = 0, 1, or 2). Remotely, the chemical stabilization propagated into the paddlewheel MBB to afford isoreticular rht-MOFs with remarkably enhanced water/chemical stabilities compared to the prototypal rht-MOF-1.

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U2 - 10.1021/acs.chemmater.5b00084

DO - 10.1021/acs.chemmater.5b00084

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SN - 0897-4756

VL - 27

SP - 2144

EP - 2151

JO - Chemistry of Materials

JF - Chemistry of Materials

IS - 6

ER -

Remote stabilization of copper paddlewheel based molecular building blocks in metal-organic frameworks

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