Solubility of β-FeF3·3H2O in mixtures of nitric and hydrofluoric acid

Kerstin M. Österdahl; Åke C. Rasmuson

doi:10.1021/je050347n

Solubility of β-FeF₃·3H₂O in mixtures of nitric and hydrofluoric acid

Kerstin M. Österdahl, Åke C. Rasmuson

KTH Royal Institute of Technology

Research output: Contribution to journal › Article › peer-review

Abstract

The solubility of β-FeF₃·3H₂O has been measured in solutions with different concentrations of nitric acid (0 to 7 m) and hydrofluoric acid (1 to 6 m) at the temperatures of (30, 40, and 50)°C. The total iron concentration at equilibrium was measured with inductively coupled plasma (ICP) spectroscopy. The solubility was evaluated in terms of the stepwise complexation of iron by fluoride ions at different ionic strength and temperature. The solubility of β-FeF₃·3H₂O increases with decreasing concentration of HF and HNO₃ and increasing temperature.

Original language	English
Pages (from-to)	223-229
Number of pages	7
Journal	Journal of Chemical and Engineering Data
Volume	51
Issue number	1
DOIs	https://doi.org/10.1021/je050347n https://doi.org/10.1021/je050347n
Publication status	Published - Jan 2006
Externally published	Yes

Access to Document

Cite this

@article{4495c47b85ff404499da83ff3fdf1513,

title = "Solubility of β-FeF3·3H2O in mixtures of nitric and hydrofluoric acid",

abstract = "The solubility of β-FeF3·3H2O has been measured in solutions with different concentrations of nitric acid (0 to 7 m) and hydrofluoric acid (1 to 6 m) at the temperatures of (30, 40, and 50)°C. The total iron concentration at equilibrium was measured with inductively coupled plasma (ICP) spectroscopy. The solubility was evaluated in terms of the stepwise complexation of iron by fluoride ions at different ionic strength and temperature. The solubility of β-FeF3·3H2O increases with decreasing concentration of HF and HNO3 and increasing temperature.",

author = "{\"O}sterdahl, {Kerstin M.} and Rasmuson, {{\AA}ke C.}",

year = "2006",

month = jan,

doi = "10.1021/je050347n",

language = "English",

volume = "51",

pages = "223--229",

journal = "Journal of Chemical and Engineering Data",

issn = "0021-9568",

number = "1",

}

TY - JOUR

T1 - Solubility of β-FeF3·3H2O in mixtures of nitric and hydrofluoric acid

AU - Österdahl, Kerstin M.

AU - Rasmuson, Åke C.

PY - 2006/1

Y1 - 2006/1

N2 - The solubility of β-FeF3·3H2O has been measured in solutions with different concentrations of nitric acid (0 to 7 m) and hydrofluoric acid (1 to 6 m) at the temperatures of (30, 40, and 50)°C. The total iron concentration at equilibrium was measured with inductively coupled plasma (ICP) spectroscopy. The solubility was evaluated in terms of the stepwise complexation of iron by fluoride ions at different ionic strength and temperature. The solubility of β-FeF3·3H2O increases with decreasing concentration of HF and HNO3 and increasing temperature.

AB - The solubility of β-FeF3·3H2O has been measured in solutions with different concentrations of nitric acid (0 to 7 m) and hydrofluoric acid (1 to 6 m) at the temperatures of (30, 40, and 50)°C. The total iron concentration at equilibrium was measured with inductively coupled plasma (ICP) spectroscopy. The solubility was evaluated in terms of the stepwise complexation of iron by fluoride ions at different ionic strength and temperature. The solubility of β-FeF3·3H2O increases with decreasing concentration of HF and HNO3 and increasing temperature.

UR - http://www.scopus.com/inward/record.url?scp=31444431895&partnerID=8YFLogxK

U2 - 10.1021/je050347n

DO - 10.1021/je050347n

M3 - Article

AN - SCOPUS:31444431895

SN - 0021-9568

VL - 51

SP - 223

EP - 229

JO - Journal of Chemical and Engineering Data

JF - Journal of Chemical and Engineering Data

IS - 1

ER -

Solubility of β-FeF₃·3H₂O in mixtures of nitric and hydrofluoric acid

Abstract

Access to Document

Other files and links

Fingerprint

Cite this