Solvent-directed control over the topology of entanglement in square lattice (sql) coordination networks

Rana Sanii; Carol Hua; Ewa Patyk-Kaźmierczak; Michael J. Zaworotko

doi:10.1039/c8cc09152h

Solvent-directed control over the topology of entanglement in square lattice (sql) coordination networks

Rana Sanii, Carol Hua, Ewa Patyk-Kaźmierczak, Michael J. Zaworotko

Department of Chemical Sciences

Research output: Contribution to journal › Article › peer-review

Abstract

We report herein that the mode of entanglement in square lattice, sql, coordination networks formed by an extended bis-imidazole ligand, L, can be controlled by the solvent used during solvothermal synthesis. [ML₂(NO₃)₂]_n (M = Co, Ni) exhibit both parallel 2D → 2D interpenetration and, unusually, mixed entanglement (parallel-inclined 2D → 3D polycatenation).

Original language	English
Pages (from-to)	1454-1457
Number of pages	4
Journal	Chemical Communications
Volume	55
Issue number	10
DOIs	https://doi.org/10.1039/c8cc09152h
Publication status	Published - 2019

Access to Document

10.1039/c8cc09152h

Cite this

@article{1bf5b72298914b4fb0abac244cf62580,

title = "Solvent-directed control over the topology of entanglement in square lattice (sql) coordination networks",

abstract = "We report herein that the mode of entanglement in square lattice, sql, coordination networks formed by an extended bis-imidazole ligand, L, can be controlled by the solvent used during solvothermal synthesis. [ML2(NO3)2]n (M = Co, Ni) exhibit both parallel 2D → 2D interpenetration and, unusually, mixed entanglement (parallel-inclined 2D → 3D polycatenation).",

author = "Rana Sanii and Carol Hua and Ewa Patyk-Ka{\'z}mierczak and Zaworotko, {Michael J.}",

note = "Publisher Copyright: {\textcopyright} 2019 The Royal Society of Chemistry.",

year = "2019",

doi = "10.1039/c8cc09152h",

language = "English",

volume = "55",

pages = "1454--1457",

journal = "Chemical Communications",

issn = "1359-7345",

number = "10",

}

TY - JOUR

T1 - Solvent-directed control over the topology of entanglement in square lattice (sql) coordination networks

AU - Sanii, Rana

AU - Hua, Carol

AU - Patyk-Kaźmierczak, Ewa

AU - Zaworotko, Michael J.

PY - 2019

Y1 - 2019

N2 - We report herein that the mode of entanglement in square lattice, sql, coordination networks formed by an extended bis-imidazole ligand, L, can be controlled by the solvent used during solvothermal synthesis. [ML2(NO3)2]n (M = Co, Ni) exhibit both parallel 2D → 2D interpenetration and, unusually, mixed entanglement (parallel-inclined 2D → 3D polycatenation).

AB - We report herein that the mode of entanglement in square lattice, sql, coordination networks formed by an extended bis-imidazole ligand, L, can be controlled by the solvent used during solvothermal synthesis. [ML2(NO3)2]n (M = Co, Ni) exhibit both parallel 2D → 2D interpenetration and, unusually, mixed entanglement (parallel-inclined 2D → 3D polycatenation).

UR - http://www.scopus.com/inward/record.url?scp=85060611018&partnerID=8YFLogxK

U2 - 10.1039/c8cc09152h

DO - 10.1039/c8cc09152h

M3 - Article

C2 - 30644471

AN - SCOPUS:85060611018

SN - 1359-7345

VL - 55

SP - 1454

EP - 1457

JO - Chemical Communications

JF - Chemical Communications

IS - 10

ER -

Solvent-directed control over the topology of entanglement in square lattice (sql) coordination networks

Abstract

Access to Document

Other files and links

Fingerprint

Cite this