Solvent-directed control over the topology of entanglement in square lattice (sql) coordination networks

Rana Sanii; Carol Hua; Ewa Patyk-Kaźmierczak; Michael J. Zaworotko

doi:10.1039/c8cc09152h

Solvent-directed control over the topology of entanglement in square lattice (sql) coordination networks

Rana Sanii
, Carol Hua
, Ewa Patyk-Kaźmierczak
, Michael J. Zaworotko

University of Limerick
University of Melbourne
Adam Mickiewicz University in Poznań

Research output: Contribution to journal › Article › peer-review

Abstract

We report herein that the mode of entanglement in square lattice, sql, coordination networks formed by an extended bis-imidazole ligand, L, can be controlled by the solvent used during solvothermal synthesis. [ML₂(NO₃)₂]_n (M = Co, Ni) exhibit both parallel 2D → 2D interpenetration and, unusually, mixed entanglement (parallel-inclined 2D → 3D polycatenation).

Original language	English
Pages (from-to)	1454-1457
Number of pages	4
Journal	Chemical Communications
Volume	55
Issue number	10
DOIs	https://doi.org/10.1039/c8cc09152h
Publication status	Published - 2019

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10.1039/c8cc09152h

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title = "Solvent-directed control over the topology of entanglement in square lattice (sql) coordination networks",

abstract = "We report herein that the mode of entanglement in square lattice, sql, coordination networks formed by an extended bis-imidazole ligand, L, can be controlled by the solvent used during solvothermal synthesis. [ML2(NO3)2]n (M = Co, Ni) exhibit both parallel 2D → 2D interpenetration and, unusually, mixed entanglement (parallel-inclined 2D → 3D polycatenation).",

author = "Rana Sanii and Carol Hua and Ewa Patyk-Ka{\'z}mierczak and Zaworotko, \{Michael J.\}",

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AU - Sanii, Rana

AU - Hua, Carol

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AU - Zaworotko, Michael J.

PY - 2019

Y1 - 2019

N2 - We report herein that the mode of entanglement in square lattice, sql, coordination networks formed by an extended bis-imidazole ligand, L, can be controlled by the solvent used during solvothermal synthesis. [ML2(NO3)2]n (M = Co, Ni) exhibit both parallel 2D → 2D interpenetration and, unusually, mixed entanglement (parallel-inclined 2D → 3D polycatenation).

AB - We report herein that the mode of entanglement in square lattice, sql, coordination networks formed by an extended bis-imidazole ligand, L, can be controlled by the solvent used during solvothermal synthesis. [ML2(NO3)2]n (M = Co, Ni) exhibit both parallel 2D → 2D interpenetration and, unusually, mixed entanglement (parallel-inclined 2D → 3D polycatenation).

UR - https://www.scopus.com/pages/publications/85060611018

U2 - 10.1039/c8cc09152h

DO - 10.1039/c8cc09152h

M3 - Article

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AN - SCOPUS:85060611018

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VL - 55

SP - 1454

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JO - Chemical Communications

JF - Chemical Communications

IS - 10

ER -

Solvent-directed control over the topology of entanglement in square lattice (sql) coordination networks

Abstract

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