State of the art and prospects of zeolites and metal organic frameworks (MOFs) for nitrogen and phosphorus removal in dairy wastewater

Water is an essential resource for humans, animals, and plants. Water is also necessary for the manufacture of many products such as milk, textiles, paper, and pharmaceutical composites. During manufacturing, some industries generate a large amount of wastewater containing numerous contaminants. In the dairy industry, for each litre of drinking milk produced, about 10 L of wastewater is generated. Despite this environmental footprint, the production of milk, butter, ice cream, baby formula, etc., are essential in many households. Common contaminants in dairy wastewater include high biological oxygen demand (BOD), chemical oxygen demand (COD), salts as well as nitrogen and phosphorus derivatives. Nitrogen and phosphorus discharges are one of the leading causes in the eutrophication of rivers and oceans. Porous materials have long held significant potential as a disruptive technology for wastewater treatment. However, thus far they have been understudied for use in dairy wastewater treatment. Ordered porous materials, such as zeolites and metal organic frameworks (MOFs), represent classes of porous materials with significant potential for the removal of nitrogen and phosphorus. This review explores the different zeolites and MOFs applied in the removal of nitrogen and phosphorus from wastewater and the prospect of their potential for use in wastewater management in the dairy industry.