Strict self-assembly of [Fe(cyclam)]3+ and [hydrogenbis(1, 1′-ferrocenedicarboxylate)]3- into a novel mixed-valent one-dimensional polymer containing an FeIIIN4O2 chromophore

Sean D. Christie, S. Subramanian, L. K. Thompson, M. J. Zaworotko

Research output: Contribution to journalArticlepeer-review

Abstract

trans-[FeIII(cyclam)][{Fc(CO2)2} 2H], 1, (cyclam = 1,4,8,11-tetraazacyclotetradecane; [Fc(CO 2)2]2- = 1,1′-ferrocenedicarboxylate) strictly self-assembles via FeIII-carboxylate covalent bonds and hydrogenbiscarboxylate hydrogen bonds to form a one-dimensional polymer that contains the first crystallographically characterized FeIIIN 4O2 chromopore.

Original languageEnglish
Pages (from-to)2563-2564
Number of pages2
JournalJournal of the Chemical Society, Chemical Communications
Issue number22
DOIs
Publication statusPublished - 1994
Externally publishedYes

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