Strict self-assembly of [Fe(cyclam)]3+ and [hydrogenbis(1, 1′-ferrocenedicarboxylate)]3- into a novel mixed-valent one-dimensional polymer containing an FeIIIN4O2 chromophore

Sean D. Christie; S. Subramanian; L. K. Thompson; M. J. Zaworotko

doi:10.1039/C39940002563

Strict self-assembly of [Fe(cyclam)]³⁺ and [hydrogenbis(1, 1′-ferrocenedicarboxylate)]^3- into a novel mixed-valent one-dimensional polymer containing an Fe^IIIN₄O₂ chromophore

Sean D. Christie
, S. Subramanian
, L. K. Thompson
, M. J. Zaworotko

Research output: Contribution to journal › Article › peer-review

Abstract

trans-[Fe^III(cyclam)][{Fc(CO₂)₂} ₂H], 1, (cyclam = 1,4,8,11-tetraazacyclotetradecane; [Fc(CO ₂)₂]^2- = 1,1′-ferrocenedicarboxylate) strictly self-assembles via Fe^III-carboxylate covalent bonds and hydrogenbiscarboxylate hydrogen bonds to form a one-dimensional polymer that contains the first crystallographically characterized Fe^IIIN ₄O₂ chromopore.

Original language	English
Pages (from-to)	2563-2564
Number of pages	2
Journal	Journal of the Chemical Society, Chemical Communications
Issue number	22
DOIs	https://doi.org/10.1039/C39940002563
Publication status	Published - 1994
Externally published	Yes

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title = "Strict self-assembly of [Fe(cyclam)]3+ and [hydrogenbis(1, 1′-ferrocenedicarboxylate)]3- into a novel mixed-valent one-dimensional polymer containing an FeIIIN4O2 chromophore",

abstract = "trans-[FeIII(cyclam)][\{Fc(CO2)2\} 2H], 1, (cyclam = 1,4,8,11-tetraazacyclotetradecane; [Fc(CO 2)2]2- = 1,1′-ferrocenedicarboxylate) strictly self-assembles via FeIII-carboxylate covalent bonds and hydrogenbiscarboxylate hydrogen bonds to form a one-dimensional polymer that contains the first crystallographically characterized FeIIIN 4O2 chromopore.",

author = "Christie, \{Sean D.\} and S. Subramanian and Thompson, \{L. K.\} and Zaworotko, \{M. J.\}",

year = "1994",

doi = "10.1039/C39940002563",

language = "English",

pages = "2563--2564",

journal = "Journal of the Chemical Society, Chemical Communications",

issn = "0022-4936",

number = "22",

}

Strict self-assembly of [Fe(cyclam)]³⁺ and [hydrogenbis(1, 1′-ferrocenedicarboxylate)]^3- into a novel mixed-valent one-dimensional polymer containing an Fe^IIIN₄O₂ chromophore. / Christie, Sean D.; Subramanian, S.; Thompson, L. K. et al.
In: Journal of the Chemical Society, Chemical Communications, No. 22, 1994, p. 2563-2564.

Research output: Contribution to journal › Article › peer-review

TY - JOUR

T1 - Strict self-assembly of [Fe(cyclam)]3+ and [hydrogenbis(1, 1′-ferrocenedicarboxylate)]3- into a novel mixed-valent one-dimensional polymer containing an FeIIIN4O2 chromophore

AU - Christie, Sean D.

AU - Subramanian, S.

AU - Thompson, L. K.

AU - Zaworotko, M. J.

PY - 1994

Y1 - 1994

N2 - trans-[FeIII(cyclam)][{Fc(CO2)2} 2H], 1, (cyclam = 1,4,8,11-tetraazacyclotetradecane; [Fc(CO 2)2]2- = 1,1′-ferrocenedicarboxylate) strictly self-assembles via FeIII-carboxylate covalent bonds and hydrogenbiscarboxylate hydrogen bonds to form a one-dimensional polymer that contains the first crystallographically characterized FeIIIN 4O2 chromopore.

AB - trans-[FeIII(cyclam)][{Fc(CO2)2} 2H], 1, (cyclam = 1,4,8,11-tetraazacyclotetradecane; [Fc(CO 2)2]2- = 1,1′-ferrocenedicarboxylate) strictly self-assembles via FeIII-carboxylate covalent bonds and hydrogenbiscarboxylate hydrogen bonds to form a one-dimensional polymer that contains the first crystallographically characterized FeIIIN 4O2 chromopore.

UR - https://www.scopus.com/pages/publications/37049079246

U2 - 10.1039/C39940002563

DO - 10.1039/C39940002563

M3 - Article

AN - SCOPUS:37049079246

SN - 0022-4936

SP - 2563

EP - 2564

JO - Journal of the Chemical Society, Chemical Communications

JF - Journal of the Chemical Society, Chemical Communications

IS - 22

ER -

Strict self-assembly of [Fe(cyclam)]³⁺ and [hydrogenbis(1, 1′-ferrocenedicarboxylate)]^3- into a novel mixed-valent one-dimensional polymer containing an Fe^IIIN₄O₂ chromophore

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