Structure of zirconia nanoparticles used for pillaring of clay

V. A. Sadykov; T. G. Kuznetsova; V. P. Doronin; T. P. Sorokina; D. I. Kochubei; B. N. Novgorodov; V. N. Kolomiichuk; E. M. Moroz; D. A. Zyuzin; E. A. Paukshtis; V. B. Fenelonov; A. Ya Derevyankin; S. A. Beloshapkin; V. A. Matyshak; G. A. Konin; J. R.H. Ross

Structure of zirconia nanoparticles used for pillaring of clay

V. A. Sadykov, T. G. Kuznetsova, V. P. Doronin, T. P. Sorokina, D. I. Kochubei, B. N. Novgorodov, V. N. Kolomiichuk, E. M. Moroz, D. A. Zyuzin, E. A. Paukshtis, V. B. Fenelonov, A. Ya Derevyankin, S. A. Beloshapkin, V. A. Matyshak, G. A. Konin, J. R.H. Ross

RAS - Boreskov Institute of Catalysis, Siberian Branch

Research output: Contribution to journal › Article › peer-review

Abstract

SAXS and EXAFS were applied to study genesis of polynuclear zirconium hydroxyspecies in pillaring solutions as dependent upon the zirconium concentration, addition of alkaline-earth chlorides and aging. After the montmorillonite clay pillaring, the structure of zirconium nanopillars was characterized by applying X-ray structural analysis, UV-Vis, FTIRS of adsorbed CO and nitrogen adsorption isotherms. Main pillaring species appear to be nanorods comprised of several Zr₄ tetramers. Basic structural features of the tetramers are preserved in zirconia nanoparticles fixed between alumosilicate layers in pillared clays. In calcined samples, those nanoparticles contain only bridging hydroxyls and/or oxygen anions responsible for bonding within pillars and between pillars and clay sheets.

Original language	English
Pages (from-to)	529-534
Number of pages	6
Journal	Materials Research Society Symposium - Proceedings
Volume	703
Publication status	Published - 2002
Externally published	Yes

Cite this

Sadykov, V. A., Kuznetsova, T. G., Doronin, V. P., Sorokina, T. P., Kochubei, D. I., Novgorodov, B. N., Kolomiichuk, V. N., Moroz, E. M., Zyuzin, D. A., Paukshtis, E. A., Fenelonov, V. B., Derevyankin, A. Y., Beloshapkin, S. A., Matyshak, V. A., Konin, G. A., & Ross, J. R. H. (2002). Structure of zirconia nanoparticles used for pillaring of clay. Materials Research Society Symposium - Proceedings, 703, 529-534.

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title = "Structure of zirconia nanoparticles used for pillaring of clay",

abstract = "SAXS and EXAFS were applied to study genesis of polynuclear zirconium hydroxyspecies in pillaring solutions as dependent upon the zirconium concentration, addition of alkaline-earth chlorides and aging. After the montmorillonite clay pillaring, the structure of zirconium nanopillars was characterized by applying X-ray structural analysis, UV-Vis, FTIRS of adsorbed CO and nitrogen adsorption isotherms. Main pillaring species appear to be nanorods comprised of several Zr4 tetramers. Basic structural features of the tetramers are preserved in zirconia nanoparticles fixed between alumosilicate layers in pillared clays. In calcined samples, those nanoparticles contain only bridging hydroxyls and/or oxygen anions responsible for bonding within pillars and between pillars and clay sheets.",

author = "Sadykov, {V. A.} and Kuznetsova, {T. G.} and Doronin, {V. P.} and Sorokina, {T. P.} and Kochubei, {D. I.} and Novgorodov, {B. N.} and Kolomiichuk, {V. N.} and Moroz, {E. M.} and Zyuzin, {D. A.} and Paukshtis, {E. A.} and Fenelonov, {V. B.} and Derevyankin, {A. Ya} and Beloshapkin, {S. A.} and Matyshak, {V. A.} and Konin, {G. A.} and Ross, {J. R.H.}",

year = "2002",

language = "English",

volume = "703",

pages = "529--534",

journal = "Materials Research Society Symposium - Proceedings",

issn = "0272-9172",

}

Sadykov, VA, Kuznetsova, TG, Doronin, VP, Sorokina, TP, Kochubei, DI, Novgorodov, BN, Kolomiichuk, VN, Moroz, EM, Zyuzin, DA, Paukshtis, EA, Fenelonov, VB, Derevyankin, AY, Beloshapkin, SA, Matyshak, VA, Konin, GA & Ross, JRH 2002, 'Structure of zirconia nanoparticles used for pillaring of clay', Materials Research Society Symposium - Proceedings, vol. 703, pp. 529-534.

TY - JOUR

T1 - Structure of zirconia nanoparticles used for pillaring of clay

AU - Sadykov, V. A.

AU - Kuznetsova, T. G.

AU - Doronin, V. P.

AU - Sorokina, T. P.

AU - Kochubei, D. I.

AU - Novgorodov, B. N.

AU - Kolomiichuk, V. N.

AU - Moroz, E. M.

AU - Zyuzin, D. A.

AU - Paukshtis, E. A.

AU - Fenelonov, V. B.

AU - Derevyankin, A. Ya

AU - Beloshapkin, S. A.

AU - Matyshak, V. A.

AU - Konin, G. A.

AU - Ross, J. R.H.

PY - 2002

Y1 - 2002

N2 - SAXS and EXAFS were applied to study genesis of polynuclear zirconium hydroxyspecies in pillaring solutions as dependent upon the zirconium concentration, addition of alkaline-earth chlorides and aging. After the montmorillonite clay pillaring, the structure of zirconium nanopillars was characterized by applying X-ray structural analysis, UV-Vis, FTIRS of adsorbed CO and nitrogen adsorption isotherms. Main pillaring species appear to be nanorods comprised of several Zr4 tetramers. Basic structural features of the tetramers are preserved in zirconia nanoparticles fixed between alumosilicate layers in pillared clays. In calcined samples, those nanoparticles contain only bridging hydroxyls and/or oxygen anions responsible for bonding within pillars and between pillars and clay sheets.

AB - SAXS and EXAFS were applied to study genesis of polynuclear zirconium hydroxyspecies in pillaring solutions as dependent upon the zirconium concentration, addition of alkaline-earth chlorides and aging. After the montmorillonite clay pillaring, the structure of zirconium nanopillars was characterized by applying X-ray structural analysis, UV-Vis, FTIRS of adsorbed CO and nitrogen adsorption isotherms. Main pillaring species appear to be nanorods comprised of several Zr4 tetramers. Basic structural features of the tetramers are preserved in zirconia nanoparticles fixed between alumosilicate layers in pillared clays. In calcined samples, those nanoparticles contain only bridging hydroxyls and/or oxygen anions responsible for bonding within pillars and between pillars and clay sheets.

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M3 - Article

AN - SCOPUS:0036353331

SN - 0272-9172

VL - 703

SP - 529

EP - 534

JO - Materials Research Society Symposium - Proceedings

JF - Materials Research Society Symposium - Proceedings

ER -

Structure of zirconia nanoparticles used for pillaring of clay

Abstract

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