Structured nanocomposite catalysts of biofuels transformation into syngas and hydrogen: Design and performance

V. Sadykov; N. Mezentseva; M. Simonov; E. Smal; M. Arapova; S. Pavlova; Y. Fedorova; O. Chub; L. Bobrova; V. Kuzmin; A. Ishchenko; T. Krieger; A. C. Roger; K. Parkhomenko; C. Mirodatos; O. Smorygo; J. Ross

doi:10.1016/j.ijhydene.2014.11.151

Structured nanocomposite catalysts of biofuels transformation into syngas and hydrogen: Design and performance

V. Sadykov
, N. Mezentseva
, M. Simonov
, E. Smal
, M. Arapova
, S. Pavlova
, Y. Fedorova
, O. Chub
, L. Bobrova
, V. Kuzmin
, A. Ishchenko
, T. Krieger
, A. C. Roger
, K. Parkhomenko
, C. Mirodatos
, O. Smorygo
, J. Ross

RAS - Boreskov Institute of Catalysis, Siberian Branch
Novosibirsk State University
Université de Strasbourg
Institut de Recherches sur la Catalyse et l'Environnement de Lyon
Powder Metallurgy Institute

Research output: Contribution to journal › Article › peer-review

Abstract

Main features of structured catalysts performance in bio-fuels reforming into syngas at lab-scale and pilot-scale levels using specially designed reactors and kinetic installations allowing to broadly tune the operational parameters are presented. Effects of the nature of nanocomposite active component comprised of Ru + Ni nanoparticles on bulk/alumina-supported perovskite or Mn-Cr-O spinel, type of substrate (Ni-Al alloy and SiC(Al₂O₃)/Al-Si-O foam substrates, Fechraloy microchannel plates or gauzes protected by thin corundum layer), type of fuel (natural gas, ethanol, acetone, ethyl acetate glycerol), feed composition and temperature on yield of syngas/byproducts and performance stability are considered. The best performance in real feeds with syngas yield approaching equilibrium at short contact times without any heat/mass transfer effects along with a high thermochemical stability were demonstrated for catalyst on heat-conducting microchannel substrate. Oxygen addition to the feed in optimized amounts allows to suppress coking and stabilize performance even for the case of such reactive fuel as glycerol only slightly affecting syngas yield.

Original language	English
Pages (from-to)	7511-7522
Number of pages	12
Journal	International Journal of Hydrogen Energy
Volume	40
Issue number	24
DOIs	https://doi.org/10.1016/j.ijhydene.2014.11.151
Publication status	Published - 29 Jun 2015

UN SDGs

This output contributes to the following UN Sustainable Development Goals (SDGs)

SDG 7 Affordable and Clean Energy

Keywords

Biofuels reforming
Catalytic performance
Coking stability
Hydrogen and syngas
Microchannel and foam substrates
Nanocomposite active components

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10.1016/j.ijhydene.2014.11.151

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Sadykov, V., Mezentseva, N., Simonov, M., Smal, E., Arapova, M., Pavlova, S., Fedorova, Y., Chub, O., Bobrova, L., Kuzmin, V., Ishchenko, A., Krieger, T., Roger, A. C., Parkhomenko, K., Mirodatos, C., Smorygo, O., & Ross, J. (2015). Structured nanocomposite catalysts of biofuels transformation into syngas and hydrogen: Design and performance. International Journal of Hydrogen Energy, 40(24), 7511-7522. https://doi.org/10.1016/j.ijhydene.2014.11.151

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title = "Structured nanocomposite catalysts of biofuels transformation into syngas and hydrogen: Design and performance",

abstract = "Main features of structured catalysts performance in bio-fuels reforming into syngas at lab-scale and pilot-scale levels using specially designed reactors and kinetic installations allowing to broadly tune the operational parameters are presented. Effects of the nature of nanocomposite active component comprised of Ru + Ni nanoparticles on bulk/alumina-supported perovskite or Mn-Cr-O spinel, type of substrate (Ni-Al alloy and SiC(Al2O3)/Al-Si-O foam substrates, Fechraloy microchannel plates or gauzes protected by thin corundum layer), type of fuel (natural gas, ethanol, acetone, ethyl acetate glycerol), feed composition and temperature on yield of syngas/byproducts and performance stability are considered. The best performance in real feeds with syngas yield approaching equilibrium at short contact times without any heat/mass transfer effects along with a high thermochemical stability were demonstrated for catalyst on heat-conducting microchannel substrate. Oxygen addition to the feed in optimized amounts allows to suppress coking and stabilize performance even for the case of such reactive fuel as glycerol only slightly affecting syngas yield.",

keywords = "Biofuels reforming, Catalytic performance, Coking stability, Hydrogen and syngas, Microchannel and foam substrates, Nanocomposite active components",

author = "V. Sadykov and N. Mezentseva and M. Simonov and E. Smal and M. Arapova and S. Pavlova and Y. Fedorova and O. Chub and L. Bobrova and V. Kuzmin and A. Ishchenko and T. Krieger and Roger, \{A. C.\} and K. Parkhomenko and C. Mirodatos and O. Smorygo and J. Ross",

note = "Publisher Copyright: {\textcopyright} 2015 Hydrogen Energy Publications, LLC.",

year = "2015",

month = jun,

day = "29",

doi = "10.1016/j.ijhydene.2014.11.151",

language = "English",

volume = "40",

pages = "7511--7522",

journal = "International Journal of Hydrogen Energy",

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Sadykov, V, Mezentseva, N, Simonov, M, Smal, E, Arapova, M, Pavlova, S, Fedorova, Y, Chub, O, Bobrova, L, Kuzmin, V, Ishchenko, A, Krieger, T, Roger, AC, Parkhomenko, K, Mirodatos, C, Smorygo, O & Ross, J 2015, 'Structured nanocomposite catalysts of biofuels transformation into syngas and hydrogen: Design and performance', International Journal of Hydrogen Energy, vol. 40, no. 24, pp. 7511-7522. https://doi.org/10.1016/j.ijhydene.2014.11.151

TY - JOUR

T1 - Structured nanocomposite catalysts of biofuels transformation into syngas and hydrogen

T2 - Design and performance

AU - Sadykov, V.

AU - Mezentseva, N.

AU - Simonov, M.

AU - Smal, E.

AU - Arapova, M.

AU - Pavlova, S.

AU - Fedorova, Y.

AU - Chub, O.

AU - Bobrova, L.

AU - Kuzmin, V.

AU - Ishchenko, A.

AU - Krieger, T.

AU - Roger, A. C.

AU - Parkhomenko, K.

AU - Mirodatos, C.

AU - Smorygo, O.

AU - Ross, J.

PY - 2015/6/29

Y1 - 2015/6/29

N2 - Main features of structured catalysts performance in bio-fuels reforming into syngas at lab-scale and pilot-scale levels using specially designed reactors and kinetic installations allowing to broadly tune the operational parameters are presented. Effects of the nature of nanocomposite active component comprised of Ru + Ni nanoparticles on bulk/alumina-supported perovskite or Mn-Cr-O spinel, type of substrate (Ni-Al alloy and SiC(Al2O3)/Al-Si-O foam substrates, Fechraloy microchannel plates or gauzes protected by thin corundum layer), type of fuel (natural gas, ethanol, acetone, ethyl acetate glycerol), feed composition and temperature on yield of syngas/byproducts and performance stability are considered. The best performance in real feeds with syngas yield approaching equilibrium at short contact times without any heat/mass transfer effects along with a high thermochemical stability were demonstrated for catalyst on heat-conducting microchannel substrate. Oxygen addition to the feed in optimized amounts allows to suppress coking and stabilize performance even for the case of such reactive fuel as glycerol only slightly affecting syngas yield.

AB - Main features of structured catalysts performance in bio-fuels reforming into syngas at lab-scale and pilot-scale levels using specially designed reactors and kinetic installations allowing to broadly tune the operational parameters are presented. Effects of the nature of nanocomposite active component comprised of Ru + Ni nanoparticles on bulk/alumina-supported perovskite or Mn-Cr-O spinel, type of substrate (Ni-Al alloy and SiC(Al2O3)/Al-Si-O foam substrates, Fechraloy microchannel plates or gauzes protected by thin corundum layer), type of fuel (natural gas, ethanol, acetone, ethyl acetate glycerol), feed composition and temperature on yield of syngas/byproducts and performance stability are considered. The best performance in real feeds with syngas yield approaching equilibrium at short contact times without any heat/mass transfer effects along with a high thermochemical stability were demonstrated for catalyst on heat-conducting microchannel substrate. Oxygen addition to the feed in optimized amounts allows to suppress coking and stabilize performance even for the case of such reactive fuel as glycerol only slightly affecting syngas yield.

KW - Biofuels reforming

KW - Catalytic performance

KW - Coking stability

KW - Hydrogen and syngas

KW - Microchannel and foam substrates

KW - Nanocomposite active components

UR - https://www.scopus.com/pages/publications/84930378540

U2 - 10.1016/j.ijhydene.2014.11.151

DO - 10.1016/j.ijhydene.2014.11.151

M3 - Article

AN - SCOPUS:84930378540

SN - 0360-3199

VL - 40

SP - 7511

EP - 7522

JO - International Journal of Hydrogen Energy

JF - International Journal of Hydrogen Energy

IS - 24

ER -

Structured nanocomposite catalysts of biofuels transformation into syngas and hydrogen: Design and performance

Abstract

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Keywords

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