TY - JOUR
T1 - Supermolecular Building Blocks (SBBs) and crystal design
T2 - 12-Connected open frameworks based on a molecular cubohemioctahedron
AU - Cairns, Amy J.
AU - Perman, Jason A.
AU - Wojtas, Lukasz
AU - Kravtsov, Victor Ch
AU - Alkordi, Mohamed H.
AU - Eddaoudi, Mohamed
AU - Zaworotko, Michael J.
PY - 2008/2/6
Y1 - 2008/2/6
N2 - The cubohemioctahedral supermolecular building blocks, SBBs, of formula [M6(bdc)12]12- (M = Ni, Co) (as illustrated) have the requisite symmetry to be cross-linked by rigid tetracarboxylato ligands in such a manner that 12-connected fcu nets with nanoscale features are generated. 3,5-H4ATC, L1, facilitates a structure with Ni that exhibits cavities with >2 nm maximum dimensions, whereas H4BIPA-TC, L2, forms a net with Co or Ni that exhibits cavities with >3 nm maximum dimensions.
AB - The cubohemioctahedral supermolecular building blocks, SBBs, of formula [M6(bdc)12]12- (M = Ni, Co) (as illustrated) have the requisite symmetry to be cross-linked by rigid tetracarboxylato ligands in such a manner that 12-connected fcu nets with nanoscale features are generated. 3,5-H4ATC, L1, facilitates a structure with Ni that exhibits cavities with >2 nm maximum dimensions, whereas H4BIPA-TC, L2, forms a net with Co or Ni that exhibits cavities with >3 nm maximum dimensions.
UR - https://www.scopus.com/pages/publications/38949158723
U2 - 10.1021/ja078060t
DO - 10.1021/ja078060t
M3 - Article
AN - SCOPUS:38949158723
SN - 0002-7863
VL - 130
SP - 1560
EP - 1561
JO - Journal of the American Chemical Society
JF - Journal of the American Chemical Society
IS - 5
ER -