TY - JOUR
T1 - Sustained Bauxite Residue Rehabilitation with Gypsum and Organic Matter 16 years after Initial Treatment
AU - Bray, Andrew W.
AU - Stewart, Douglas I.
AU - Courtney, Ronan
AU - Rout, Simon P.
AU - Humphreys, Paul N.
AU - Mayes, William M.
AU - Burke, Ian T.
N1 - Publisher Copyright:
© 2017 American Chemical Society.
PY - 2018/1/2
Y1 - 2018/1/2
N2 - Bauxite residue is a high volume byproduct of alumina manufacture which is commonly disposed of in purpose-built bauxite residue disposal areas (BRDAs). Natural waters interacting with bauxite residue are characteristically highly alkaline, and have elevated concentrations of Na, Al, and other trace metals. Rehabilitation of BRDAs is therefore often costly and resource/infrastructure intensive. Data is presented from three neighboring plots of bauxite residue that was deposited 20 years ago. One plot was amended 16 years ago with process sand, organic matter, gypsum, and seeded (fully treated), another plot was amended 16 years ago with process sand, organic matter, and seeded (partially treated), and a third plot was left untreated. These surface treatments lower alkalinity and salinity, and thus produce a substrate more suitable for biological colonisation from seeding. The reduction of pH leads to much lower Al, V, and As mobility in the actively treated residue and the beneficial effects of treatment extend passively 20-30 cm below the depth of the original amendment. These positive rehabilitation effects are maintained after 2 decades due to the presence of an active and resilient biological community. This treatment may provide a lower cost solution to BRDA end of use closure plans and orphaned BRDA rehabilitation.
AB - Bauxite residue is a high volume byproduct of alumina manufacture which is commonly disposed of in purpose-built bauxite residue disposal areas (BRDAs). Natural waters interacting with bauxite residue are characteristically highly alkaline, and have elevated concentrations of Na, Al, and other trace metals. Rehabilitation of BRDAs is therefore often costly and resource/infrastructure intensive. Data is presented from three neighboring plots of bauxite residue that was deposited 20 years ago. One plot was amended 16 years ago with process sand, organic matter, gypsum, and seeded (fully treated), another plot was amended 16 years ago with process sand, organic matter, and seeded (partially treated), and a third plot was left untreated. These surface treatments lower alkalinity and salinity, and thus produce a substrate more suitable for biological colonisation from seeding. The reduction of pH leads to much lower Al, V, and As mobility in the actively treated residue and the beneficial effects of treatment extend passively 20-30 cm below the depth of the original amendment. These positive rehabilitation effects are maintained after 2 decades due to the presence of an active and resilient biological community. This treatment may provide a lower cost solution to BRDA end of use closure plans and orphaned BRDA rehabilitation.
UR - http://www.scopus.com/inward/record.url?scp=85040166082&partnerID=8YFLogxK
U2 - 10.1021/acs.est.7b03568
DO - 10.1021/acs.est.7b03568
M3 - Article
C2 - 29182867
AN - SCOPUS:85040166082
SN - 0013-936X
VL - 52
SP - 152
EP - 161
JO - Environmental Science and Technology
JF - Environmental Science and Technology
IS - 1
ER -