TY - JOUR
T1 - Synthesis and molecular structures of chloro(trimethylphosphine) tris(trimethylsilylmethyl)molybdenum(IV) and di-μ-chloro- bis[η2-trimethylsilylmethylcarbonylbis(carbonyl) trimethylphosphine-molybdenum(II)]
AU - Guzman, Ernesto Carmona
AU - Wilkinson, Geoffrey
AU - Atwood, Jerry L.
AU - Rogers, Robin D.
AU - Hunter, William E.
AU - Zaworotko, Michael J.
PY - 1978
Y1 - 1978
N2 - The interaction of bis(trimethylsilylmethyl)-magnesium and molybdenum tetrachloridebis(tetrahydrofuran) in the presence of trimethylphosphine gives a 5-co-ordinate molybdenum(IV) alkyl MoCl(CH2SiMe3) 3PMe3 which reacts with carbon monoxide to give a molybdenum(II) chlorine-bridged dimer [MoCl(η2-COCH 2SiMe3)(CO)2PMe3]2; the structures of both complexes have been determined by X-ray crystallography and the dimer shown to have a bidentate η2-acyl group.
AB - The interaction of bis(trimethylsilylmethyl)-magnesium and molybdenum tetrachloridebis(tetrahydrofuran) in the presence of trimethylphosphine gives a 5-co-ordinate molybdenum(IV) alkyl MoCl(CH2SiMe3) 3PMe3 which reacts with carbon monoxide to give a molybdenum(II) chlorine-bridged dimer [MoCl(η2-COCH 2SiMe3)(CO)2PMe3]2; the structures of both complexes have been determined by X-ray crystallography and the dimer shown to have a bidentate η2-acyl group.
UR - http://www.scopus.com/inward/record.url?scp=37049092715&partnerID=8YFLogxK
U2 - 10.1039/C39780000465
DO - 10.1039/C39780000465
M3 - Article
AN - SCOPUS:37049092715
SN - 0022-4936
SP - 465
EP - 466
JO - Journal of the Chemical Society, Chemical Communications
JF - Journal of the Chemical Society, Chemical Communications
IS - 11
ER -