TY - JOUR
T1 - Synthesis, characterisation and X-ray structure of a mononuclear zinc(II)azido complex containing tetradentate schiff base
AU - Banerjee, Jaya
AU - Bose, Doyel
AU - Rahaman, Sk Hafijur
AU - Bailey Walsh, Rosa D.
AU - Zaworotko, M. J.
AU - Ghosh, Barindra K.
PY - 2004/5
Y1 - 2004/5
N2 - The synthesis, characterisation and single crystal X-ray structural analysis of [Zn(bnbzpy)(N3)]ClO4 (1) [bnbzpy = N,N′-(bis(pyridin-2-yl)benzylidene)butane-1,4-diamine] have been described. X-ray diffraction study has been made for the exact definition of the coordination sphere. Structural analysis reveals that the zinc(II) centre in mononuclear 1 is in a distorted trigonal bipyramidal ZnN5 environment ligated by four N atoms of the organic blocker and the terminal azide. The tetradentate chelator is folded in the butylenic part.
AB - The synthesis, characterisation and single crystal X-ray structural analysis of [Zn(bnbzpy)(N3)]ClO4 (1) [bnbzpy = N,N′-(bis(pyridin-2-yl)benzylidene)butane-1,4-diamine] have been described. X-ray diffraction study has been made for the exact definition of the coordination sphere. Structural analysis reveals that the zinc(II) centre in mononuclear 1 is in a distorted trigonal bipyramidal ZnN5 environment ligated by four N atoms of the organic blocker and the terminal azide. The tetradentate chelator is folded in the butylenic part.
UR - http://www.scopus.com/inward/record.url?scp=2942726482&partnerID=8YFLogxK
M3 - Article
AN - SCOPUS:2942726482
SN - 0376-4710
VL - 43
SP - 1119
EP - 1122
JO - Indian Journal of Chemistry - Section A Inorganic, Physical, Theoretical and Analytical Chemistry
JF - Indian Journal of Chemistry - Section A Inorganic, Physical, Theoretical and Analytical Chemistry
IS - 5
ER -