Synthesis, characterisation and X-ray structure of a mononuclear zinc(II)azido complex containing tetradentate schiff base

Jaya Banerjee; Doyel Bose; Sk Hafijur Rahaman; Rosa D. Bailey Walsh; M. J. Zaworotko; Barindra K. Ghosh

Synthesis, characterisation and X-ray structure of a mononuclear zinc(II)azido complex containing tetradentate schiff base

Jaya Banerjee
, Doyel Bose
, Sk Hafijur Rahaman
, Rosa D. Bailey Walsh
, M. J. Zaworotko
, Barindra K. Ghosh

Research output: Contribution to journal › Article › peer-review

Abstract

The synthesis, characterisation and single crystal X-ray structural analysis of [Zn(bnbzpy)(N₃)]ClO₄ (1) [bnbzpy = N,N′-(bis(pyridin-2-yl)benzylidene)butane-1,4-diamine] have been described. X-ray diffraction study has been made for the exact definition of the coordination sphere. Structural analysis reveals that the zinc(II) centre in mononuclear 1 is in a distorted trigonal bipyramidal ZnN₅ environment ligated by four N atoms of the organic blocker and the terminal azide. The tetradentate chelator is folded in the butylenic part.

Original language	English
Pages (from-to)	1119-1122
Number of pages	4
Journal	Indian Journal of Chemistry - Section A Inorganic, Physical, Theoretical and Analytical Chemistry
Volume	43
Issue number	5
Publication status	Published - May 2004
Externally published	Yes

Cite this

@article{1107ccb3187f4ebd96ca2fe8d71e0012,

title = "Synthesis, characterisation and X-ray structure of a mononuclear zinc(II)azido complex containing tetradentate schiff base",

abstract = "The synthesis, characterisation and single crystal X-ray structural analysis of [Zn(bnbzpy)(N3)]ClO4 (1) [bnbzpy = N,N′-(bis(pyridin-2-yl)benzylidene)butane-1,4-diamine] have been described. X-ray diffraction study has been made for the exact definition of the coordination sphere. Structural analysis reveals that the zinc(II) centre in mononuclear 1 is in a distorted trigonal bipyramidal ZnN5 environment ligated by four N atoms of the organic blocker and the terminal azide. The tetradentate chelator is folded in the butylenic part.",

author = "Jaya Banerjee and Doyel Bose and Rahaman, \{Sk Hafijur\} and \{Bailey Walsh\}, \{Rosa D.\} and Zaworotko, \{M. J.\} and Ghosh, \{Barindra K.\}",

year = "2004",

month = may,

language = "English",

volume = "43",

pages = "1119--1122",

journal = "Indian Journal of Chemistry - Section A Inorganic, Physical, Theoretical and Analytical Chemistry",

issn = "0376-4710",

number = "5",

}

Synthesis, characterisation and X-ray structure of a mononuclear zinc(II)azido complex containing tetradentate schiff base. / Banerjee, Jaya; Bose, Doyel; Rahaman, Sk Hafijur et al.
In: Indian Journal of Chemistry - Section A Inorganic, Physical, Theoretical and Analytical Chemistry, Vol. 43, No. 5, 05.2004, p. 1119-1122.

Research output: Contribution to journal › Article › peer-review

TY - JOUR

T1 - Synthesis, characterisation and X-ray structure of a mononuclear zinc(II)azido complex containing tetradentate schiff base

AU - Banerjee, Jaya

AU - Bose, Doyel

AU - Rahaman, Sk Hafijur

AU - Bailey Walsh, Rosa D.

AU - Zaworotko, M. J.

AU - Ghosh, Barindra K.

PY - 2004/5

Y1 - 2004/5

N2 - The synthesis, characterisation and single crystal X-ray structural analysis of [Zn(bnbzpy)(N3)]ClO4 (1) [bnbzpy = N,N′-(bis(pyridin-2-yl)benzylidene)butane-1,4-diamine] have been described. X-ray diffraction study has been made for the exact definition of the coordination sphere. Structural analysis reveals that the zinc(II) centre in mononuclear 1 is in a distorted trigonal bipyramidal ZnN5 environment ligated by four N atoms of the organic blocker and the terminal azide. The tetradentate chelator is folded in the butylenic part.

AB - The synthesis, characterisation and single crystal X-ray structural analysis of [Zn(bnbzpy)(N3)]ClO4 (1) [bnbzpy = N,N′-(bis(pyridin-2-yl)benzylidene)butane-1,4-diamine] have been described. X-ray diffraction study has been made for the exact definition of the coordination sphere. Structural analysis reveals that the zinc(II) centre in mononuclear 1 is in a distorted trigonal bipyramidal ZnN5 environment ligated by four N atoms of the organic blocker and the terminal azide. The tetradentate chelator is folded in the butylenic part.

UR - https://www.scopus.com/pages/publications/2942726482

M3 - Article

AN - SCOPUS:2942726482

SN - 0376-4710

VL - 43

SP - 1119

EP - 1122

JO - Indian Journal of Chemistry - Section A Inorganic, Physical, Theoretical and Analytical Chemistry

JF - Indian Journal of Chemistry - Section A Inorganic, Physical, Theoretical and Analytical Chemistry

IS - 5

ER -

Synthesis, characterisation and X-ray structure of a mononuclear zinc(II)azido complex containing tetradentate schiff base

Abstract

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