Synthesis, structure and selective upper rim functionalization of long chained alkoxythiacalix[4]arenes

Oleg Kasyan, Elisabeth R. Healey, Andriy Drapailo, Mike Zaworotko, Sebastien Cecillon, Anthony W. Coleman, Vitaly Kalchenko

Research output: Contribution to journalArticlepeer-review

Abstract

The synthesis and X-ray structure investigation of the cone shaped monodecyloxythiacalix[4]arene, as well as the introduction of the reactive bromide or chloromethyl groups on it's upper rim are described. Preparation of the amphiphilic derivative of thiacalixarene bearing three hydrophilic diethoxyphosphoryl groups at the upper rim and lipophilic decyloxy group at the lower rim is presented.

Original languageEnglish
Pages (from-to)127-132
Number of pages6
JournalJournal of Inclusion Phenomena and Macrocyclic Chemistry
Volume58
Issue number1-2
DOIs
Publication statusPublished - Jun 2007
Externally publishedYes

Keywords

  • Amphiphilic calixarene
  • Langmuir-Blodgett film
  • Thiacalixarene
  • X-ray analysis

Fingerprint

Dive into the research topics of 'Synthesis, structure and selective upper rim functionalization of long chained alkoxythiacalix[4]arenes'. Together they form a unique fingerprint.

Cite this