Synthesis, structure and selective upper rim functionalization of long chained alkoxythiacalix[4]arenes

Oleg Kasyan; Elisabeth R. Healey; Andriy Drapailo; Mike Zaworotko; Sebastien Cecillon; Anthony W. Coleman; Vitaly Kalchenko

doi:10.1007/s10847-006-9134-x

Synthesis, structure and selective upper rim functionalization of long chained alkoxythiacalix[4]arenes

Oleg Kasyan
, Elisabeth R. Healey
, Andriy Drapailo
, Mike Zaworotko
, Sebastien Cecillon
, Anthony W. Coleman
, Vitaly Kalchenko

NASU - Institute of Organic Chemistry
University of South Florida
CNRS UMR5086

Research output: Contribution to journal › Article › peer-review

Abstract

The synthesis and X-ray structure investigation of the cone shaped monodecyloxythiacalix[4]arene, as well as the introduction of the reactive bromide or chloromethyl groups on it's upper rim are described. Preparation of the amphiphilic derivative of thiacalixarene bearing three hydrophilic diethoxyphosphoryl groups at the upper rim and lipophilic decyloxy group at the lower rim is presented.

Original language	English
Pages (from-to)	127-132
Number of pages	6
Journal	Journal of Inclusion Phenomena and Macrocyclic Chemistry
Volume	58
Issue number	1-2
DOIs	https://doi.org/10.1007/s10847-006-9134-x
Publication status	Published - Jun 2007
Externally published	Yes

Keywords

Amphiphilic calixarene
Langmuir-Blodgett film
Thiacalixarene
X-ray analysis

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10.1007/s10847-006-9134-x

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title = "Synthesis, structure and selective upper rim functionalization of long chained alkoxythiacalix[4]arenes",

abstract = "The synthesis and X-ray structure investigation of the cone shaped monodecyloxythiacalix[4]arene, as well as the introduction of the reactive bromide or chloromethyl groups on it's upper rim are described. Preparation of the amphiphilic derivative of thiacalixarene bearing three hydrophilic diethoxyphosphoryl groups at the upper rim and lipophilic decyloxy group at the lower rim is presented.",

keywords = "Amphiphilic calixarene, Langmuir-Blodgett film, Thiacalixarene, X-ray analysis",

author = "Oleg Kasyan and Healey, \{Elisabeth R.\} and Andriy Drapailo and Mike Zaworotko and Sebastien Cecillon and Coleman, \{Anthony W.\} and Vitaly Kalchenko",

year = "2007",

month = jun,

doi = "10.1007/s10847-006-9134-x",

language = "English",

volume = "58",

pages = "127--132",

journal = "Journal of Inclusion Phenomena and Macrocyclic Chemistry",

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TY - JOUR

T1 - Synthesis, structure and selective upper rim functionalization of long chained alkoxythiacalix[4]arenes

AU - Kasyan, Oleg

AU - Healey, Elisabeth R.

AU - Drapailo, Andriy

AU - Zaworotko, Mike

AU - Cecillon, Sebastien

AU - Coleman, Anthony W.

AU - Kalchenko, Vitaly

PY - 2007/6

Y1 - 2007/6

N2 - The synthesis and X-ray structure investigation of the cone shaped monodecyloxythiacalix[4]arene, as well as the introduction of the reactive bromide or chloromethyl groups on it's upper rim are described. Preparation of the amphiphilic derivative of thiacalixarene bearing three hydrophilic diethoxyphosphoryl groups at the upper rim and lipophilic decyloxy group at the lower rim is presented.

AB - The synthesis and X-ray structure investigation of the cone shaped monodecyloxythiacalix[4]arene, as well as the introduction of the reactive bromide or chloromethyl groups on it's upper rim are described. Preparation of the amphiphilic derivative of thiacalixarene bearing three hydrophilic diethoxyphosphoryl groups at the upper rim and lipophilic decyloxy group at the lower rim is presented.

KW - Amphiphilic calixarene

KW - Langmuir-Blodgett film

KW - Thiacalixarene

KW - X-ray analysis

UR - https://www.scopus.com/pages/publications/34247349967

U2 - 10.1007/s10847-006-9134-x

DO - 10.1007/s10847-006-9134-x

M3 - Article

AN - SCOPUS:34247349967

SN - 0923-0750

VL - 58

SP - 127

EP - 132

JO - Journal of Inclusion Phenomena and Macrocyclic Chemistry

JF - Journal of Inclusion Phenomena and Macrocyclic Chemistry

IS - 1-2

ER -

Synthesis, structure and selective upper rim functionalization of long chained alkoxythiacalix[4]arenes

Abstract

Keywords

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