Tar from pilot scale co-pyrolysis of biological dairy sludge and spruce wood chips

Research output: Contribution to journalConference articlepeer-review

Abstract

A pilot scale investigation of co-pyrolysis of biological dairy sludge and spruce wood chips and pyrolysis of spruce wood chips solely was carried out. Pyrolysis was tested as a waste treatment method aiming to reduce the volume of dairy sludge while producing a pyrolysis gas suitable for an internal combustion engine. Pyrolysis tests were carried out in a continuously fed, pilot scale rotating retort type of facility in the temperature range between 700 and 770 °C. Feedstock feeding rates were between 40.9 - 68.6 kgd.a.f. h-1. Tar yields and composition was measured by means of the solid phase adsorption method in order to assess gas quality with regard to the specified tar limits given for downstream applications. The yields of total gas chromatography detectable tar produced from the dairy sludge and spruce wood chips blend was in the range between 7.25 - 10.98 gtotal tar Nm-3 dry raw gas, while spruce wood chips solely produced yields between 11.18 - 13.31 gtotal tar Nm-3 dry raw gas. Composition wise, the main difference was a number of nitrogen-containing tar compounds reflecting the high nitrogen content in dairy sludge feedstock with 2-butenenitrile, pyridine and 1H-pyrrole being the most abundant nitrogen-containing tar compounds. Raw pyrolysis gas from the two feedstocks tested did not meet the requirements regarding tar limits given in the manufacturer's specification for their internal combustion engine. The raw pyrolysis gas contained excessive amounts of 3 and 4+ aromatic ring tars. Therefore tar removal is required prior to combustion in the engine. The proposed tar removal strategy includes a thermal tar reformer using air as a reforming agent followed by adsorption using wood chips, or in-process generated bio-char, or torrefied biomass as a viable adsorbent.

Original languageEnglish
Pages (from-to)66-74
Number of pages9
JournalEnergy Procedia
Volume161
DOIs
Publication statusPublished - 2019
Event2nd International Conference on Sustainable Energy and Resource Use in Food Chains, ICSEF 2018 - Paphos, Cyprus
Duration: 17 Oct 201819 Oct 2018

Keywords

  • Dairy processing sludge
  • Pyrolysis
  • Tar
  • Waste treatment

Fingerprint

Dive into the research topics of 'Tar from pilot scale co-pyrolysis of biological dairy sludge and spruce wood chips'. Together they form a unique fingerprint.

Cite this