Temperature-dependent guest reorientation: A reversible order-disorder transformation in a single crystal

Matteo Lusi; Leonard J. Barbour

doi:10.1039/c3ce41572d

Temperature-dependent guest reorientation: A reversible order-disorder transformation in a single crystal

Matteo Lusi, Leonard J. Barbour

Department of Chemical Sciences

Stellenbosch University

Research output: Contribution to journal › Article › peer-review

Abstract

A Werner clathrate undergoes a reversible, temperature-induced, single-crystal to single-crystal polymorphic transformation. Such transformation involves a realignment of the Werner complex, which generates a twofold axis and increases the space group symmetry from P2₁/n to C2/c. An increase of the crystal's dynamic disorder is also associated with the phase transition. Crystallographic and thermal behaviours are discussed.

Original language	English
Pages (from-to)	36-38
Number of pages	3
Journal	CrystEngComm
Volume	16
Issue number	1
DOIs	https://doi.org/10.1039/c3ce41572d
Publication status	Published - 7 Jan 2014

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abstract = "A Werner clathrate undergoes a reversible, temperature-induced, single-crystal to single-crystal polymorphic transformation. Such transformation involves a realignment of the Werner complex, which generates a twofold axis and increases the space group symmetry from P21/n to C2/c. An increase of the crystal's dynamic disorder is also associated with the phase transition. Crystallographic and thermal behaviours are discussed.",

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AB - A Werner clathrate undergoes a reversible, temperature-induced, single-crystal to single-crystal polymorphic transformation. Such transformation involves a realignment of the Werner complex, which generates a twofold axis and increases the space group symmetry from P21/n to C2/c. An increase of the crystal's dynamic disorder is also associated with the phase transition. Crystallographic and thermal behaviours are discussed.

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Temperature-dependent guest reorientation: A reversible order-disorder transformation in a single crystal

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