TY - JOUR
T1 - Template-directed synthesis of nets based upon octahemioctahedral cages that encapsulate catalytically active metalloporphyrins
AU - Zhang, Zhenjie
AU - Zhang, Linping
AU - Wojtas, Lukasz
AU - Eddaoudi, Mohamed
AU - Zaworotko, Michael J.
PY - 2012/1/18
Y1 - 2012/1/18
N2 - meso-Tetra(N-methyl-4-pyridyl)porphine tetratosylate (TMPyP) templates the synthesis of six new metal-organic materials by the reaction of benzene-1,3,5-tricarboxylate with transition metals, five of which exhibit HKUST-1 or tbo topology (M = Fe, Mn, Co, Ni, Mg). The resulting materials, porph@MOMs, selectively encapsulate the corresponding metalloporphyrins in octahemioctahedral cages and can serve as size-selective heterogeneous catalysts for oxidation of olefins.
AB - meso-Tetra(N-methyl-4-pyridyl)porphine tetratosylate (TMPyP) templates the synthesis of six new metal-organic materials by the reaction of benzene-1,3,5-tricarboxylate with transition metals, five of which exhibit HKUST-1 or tbo topology (M = Fe, Mn, Co, Ni, Mg). The resulting materials, porph@MOMs, selectively encapsulate the corresponding metalloporphyrins in octahemioctahedral cages and can serve as size-selective heterogeneous catalysts for oxidation of olefins.
UR - http://www.scopus.com/inward/record.url?scp=84862910982&partnerID=8YFLogxK
U2 - 10.1021/ja208256u
DO - 10.1021/ja208256u
M3 - Article
AN - SCOPUS:84862910982
SN - 0002-7863
VL - 134
SP - 928
EP - 933
JO - Journal of the American Chemical Society
JF - Journal of the American Chemical Society
IS - 2
ER -