TY - JOUR
T1 - Templated synthesis, postsynthetic metal exchange, and properties of a porphyrin-encapsulating metal-organic material
AU - Zhang, Zhenjie
AU - Zhang, Linping
AU - Wojtas, Lukasz
AU - Nugent, Patrick
AU - Eddaoudi, Mohamed
AU - Zaworotko, Michael J.
PY - 2012/1/18
Y1 - 2012/1/18
N2 - Reaction of biphenyl-3,4′,5-tricarboxylate (H 3BPT) and CdCl 2 in the presence of meso-tetra(N-methyl-4-pyridyl)porphine tetratosylate (TMPyP) afforded porph@MOM-10, a microporous metal-organic material containing CdTMPyP cations encapsulated in an anionic Cd(II) carboxylate framework, [Cd 6(BPT) 4Cl 4(H 2O) 4]. Porph@MOM-10 is a versatile platform that undergoes exchange to serve as the parent of a series of porph@MOMs that exhibit permanent porosity and heterogeneous catalytic activity.
AB - Reaction of biphenyl-3,4′,5-tricarboxylate (H 3BPT) and CdCl 2 in the presence of meso-tetra(N-methyl-4-pyridyl)porphine tetratosylate (TMPyP) afforded porph@MOM-10, a microporous metal-organic material containing CdTMPyP cations encapsulated in an anionic Cd(II) carboxylate framework, [Cd 6(BPT) 4Cl 4(H 2O) 4]. Porph@MOM-10 is a versatile platform that undergoes exchange to serve as the parent of a series of porph@MOMs that exhibit permanent porosity and heterogeneous catalytic activity.
UR - http://www.scopus.com/inward/record.url?scp=84862907672&partnerID=8YFLogxK
U2 - 10.1021/ja209643b
DO - 10.1021/ja209643b
M3 - Article
AN - SCOPUS:84862907672
SN - 0002-7863
VL - 134
SP - 924
EP - 927
JO - Journal of the American Chemical Society
JF - Journal of the American Chemical Society
IS - 2
ER -